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Fundamentals of Biomolecules and Bonding

Dec 14, 2025

Overview

  • Biomolecules are chemical compounds common to all living organisms.
  • Carbon's bonding versatility underlies biomolecule structure and diversity.
  • Functional groups determine biomolecule reactivity and identity.
  • Four main biomolecule classes: proteins, carbohydrates, nucleic acids, lipids.

Carbon Structure And Bonding

  • Carbon forms stable bonds with H, O, N, P, and S.
  • Carbon can bond to itself, forming chains, branched chains, and rings.
  • Carbon can form single or double bonds with itself or other elements.
  • The carbon chain of a biomolecule is called its skeleton or backbone.

Functional Groups

  • Definition: specific bonded-atom groups with consistent chemical properties and predictable reactions.
  • Functional groups attach to the carbon backbone (shown as R in diagrams).
  • Presence of a functional group changes chemical reactivity and helps identify the biomolecule.

Common Functional Groups In Biology

  • Hydroxyl (–OH)
    • Example: attachment to a carbon skeleton yields ethanol.
  • Carboxyl (–COOH)
    • Example: attachment to a carbon backbone can form a fatty acid.
  • Amino (–NH2)
    • Example: together with a carboxyl group on a backbone forms an amino acid.
  • Sulfhydryl (–SH)
  • Phosphate (–PO4^3-)

Biomolecule Classes

  • Proteins
    • Composed of amino acids (contain amino and carboxyl groups).
  • Carbohydrates
    • Built on carbon backbones with various functional groups.
  • Nucleic Acids
    • Contain phosphate groups and nitrogenous bases attached to a sugar backbone.
  • Lipids
    • Often include long hydrocarbon (carbon) chains and carboxyl groups in fatty acids.

Key Terms And Definitions

| Term | Definition | | Biomolecule | Chemical compound common to living organisms, containing carbon-based bonds. | | Carbon Skeleton / Backbone | The chain of carbon atoms that defines a molecule’s shape. | | Functional Group | Specific bonded atoms that confer characteristic chemical properties. | | Hydroxyl | –OH functional group; increases polarity and reactivity. | | Carboxyl | –COOH functional group; acidic, found in fatty acids and amino acids. | | Amino | –NH2 functional group; basic, found in amino acids. | | Sulfhydryl | –SH functional group; can form disulfide bonds in proteins. | | Phosphate | –PO4 functional group; important in nucleic acids and energy transfer. |

Examples And Connections

  • Methane (CH4) illustrates a simple carbon bonded to four hydrogens.
  • Ethanol example: carbon backbone + hydroxyl group → ethanol.
  • Fatty acid example: carbon backbone + carboxyl group → fatty acid.
  • Amino acid example: carbon backbone + amino + carboxyl groups → amino acid.

Action Items / Next Steps

  • Review detailed structures and properties of proteins, carbohydrates, nucleic acids, and lipids in upcoming tutorials.
  • Learn common reactions associated with each functional group.
  • Practice identifying functional groups and carbon skeletons in molecular diagrams.