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Fundamentals of Atomic Structure

Dec 11, 2025

Overview

  • Quiz-style lecture reviewing basic atomic structure and related concepts.
  • Covers particle locations, charges, masses, forces in the atom, ions, and examples with aluminum.

Atomic Structure

  • Atom consists of nucleus (center) and electron cloud (outside).
  • Nucleus contains protons (positive) and neutrons (neutral).
  • Electrons (negative) orbit outside the nucleus and form the electron cloud.
  • Atoms are mostly empty space; nucleus is very small compared to electron cloud.
  • About 99% of an atom's mass is concentrated in the nucleus.

Key Particles, Charges, And Masses

  • Protons: carry +1 charge; located in nucleus.
  • Neutrons: electrically neutral (0 charge); located in nucleus.
  • Electrons: carry −1 charge; located outside nucleus in orbit/cloud.
  • Relative masses (SI units):
    • Proton: 1.672 × 10^−27 kg
    • Neutron: 1.6749 × 10^−27 kg (slightly heavier than proton)
    • Electron: 9.11 × 10^−31 kg (much lighter)
  • Relative masses (approx. atomic mass units):
    • Proton ≈ 1 amu
    • Neutron ≈ 1 amu
    • Electron ≈ 0.000549 amu
  • Atomic mass of an element is based on number of protons + neutrons; electron mass is negligible.

Forces And Electron Behavior

  • Opposite charges attract; like charges repel.
  • Electrostatic force attracts electrons toward nucleus.
  • Electrons remain in orbit due to their tangential velocity combined with electrostatic attraction.
  • If an electron gains enough energy (e.g., absorbs a photon), it can escape the atom → ionization (forms an ion).
  • Electron capture: an electron falls into the nucleus in certain nuclear reactions, changing the element.
  • Strong nuclear force (strong force) binds protons and neutrons in nucleus; much stronger than electrostatic repulsion, preventing protons from flying apart.

Ions And Charge Calculations

  • Net charge = (number of protons × +1) + (number of electrons × −1).
  • Example: Ion with 12 protons and 9 electrons → net charge = +12 + (−9) = +3.
  • Atoms under standard conditions are electrically neutral (equal protons and electrons).
  • Ions have unequal numbers of protons and electrons and therefore net positive or negative charge.
  • Positive ion = cation; negative ion = anion.

Example: Aluminum (Al)

  • Aluminum isotope example: Aluminum-27 (mass number 27, atomic number 13).
  • Atomic number (13) = number of protons.
  • Number of neutrons = mass number − atomic number = 27 − 13 = 14.
  • For neutral aluminum: electrons = atomic number = 13.
  • For Al^3+ ion: electrons = atomic number − charge = 13 − 3 = 10.
  • Neutral atoms are electrically neutral because protons = electrons.

Key Terms And Definitions

  • Nucleus: central region containing protons and neutrons.
  • Electron Cloud/Orbit: region where electrons move around nucleus.
  • Proton: positively charged subatomic particle, ~1 amu.
  • Neutron: neutral subatomic particle, ~1 amu, slightly heavier than proton.
  • Electron: negatively charged subatomic particle, negligible mass relative to nucleus.
  • Ion: atom with unequal numbers of protons and electrons (net charge).
  • Cation: positively charged ion.
  • Anion: negatively charged ion.
  • Electron Capture: process where an electron is absorbed into the nucleus.
  • Ionization: removal of an electron from an atom, creating an ion.
  • Strong Nuclear Force: force that holds nucleus together, stronger than electrostatic force.

Action Items / Next Steps

  • Practice identifying particle locations and charges for various elements.
  • Compute net charges for different proton/electron combinations.
  • Convert between mass numbers, atomic numbers, and numbers of neutrons for isotopes.
  • Review electron capture and ionization examples for conceptual understanding.