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1.8 - electronic structure

Nov 1, 2025

Overview

This lesson explains how electrons arrange in shells around atomic nuclei and why incomplete outer shells make most atoms unstable and reactive.

Electron Shell Fundamentals

  • Electrons occupy shells (energy levels) arranged as rings around the nucleus
  • First shell holds maximum 2 electrons; second and third shells hold maximum 8 each
  • Shells fill from innermost to outermost (lowest to highest energy)
  • Draw electrons as crosses (×) or dots (•) in diagrams

Drawing Electron Arrangements

  • Atomic number reveals both proton count and electron count for neutral atoms
  • Add electrons clockwise in positions: top, right, bottom, left
  • Place one electron per position before pairing any electrons
  • Continue adding until shell is full or electrons are exhausted

Atomic Stability

  • Atoms are stable when their outermost shell is completely full
  • Incomplete outer shells make atoms unstable and chemically reactive
  • Unstable atoms react with others to gain, lose, or share electrons

Electron Arrangement Examples

ElementAtomic NumberElectron ArrangementOuter Shell Status
Sodium112, 8, 1Unstable (1 of 8 electrons)
Neon102, 8Stable (full outer shell)
Argon182, 8, 8Stable (full outer shell)
Calcium202, 8, 8, 2Unstable (2 of 8 electrons)
Fluorine92, 7Unstable (7 of 8 electrons)

Noble Gases

  • Group 0 elements have completely full outer shells (e.g., neon, argon)
  • Stable configuration means they do not gain or lose electrons
  • Exceptionally unreactive; do not form compounds under normal conditions

Ion Formation

  • Ions form when atoms lose or gain electrons to achieve stable outer shells
  • Losing electrons creates positive ions (fewer electrons than protons)
  • Gaining electrons creates negative ions (more electrons than protons)
  • Draw square brackets around ion diagrams with charge in top right

Calcium Ion Example

  • Calcium atom (2, 8, 8, 2) loses 2 outer electrons
  • Results in Ca²⁺ ion with arrangement 2, 8, 8
  • 20 protons but only 18 electrons create 2+ charge
  • Third shell becomes full outermost shell, achieving stability

Fluorine Ion Example

  • Fluorine atom (2, 7) gains 1 electron to complete outer shell
  • Results in F⁻ ion with arrangement 2, 8
  • 9 protons but 10 electrons create 1- charge
  • Full outer shell provides stability

Key Terms & Definitions

  • Electron arrangement: Distribution of electrons across shells around the nucleus
  • Outer shell: Furthest shell from nucleus; must be full for stability
  • Ion: Charged particle formed when atom gains or loses electrons
  • Noble gases: Group 0 elements with full outer shells; unreactive