Ch 2 Overview of Fundamental Chemistry Concepts

Sep 1, 2024

Lecture Notes: Chapter 2 - Chemistry Overview

Introduction to Chemistry

  • Definition: Chemistry involves all elements and how they interact with the world.
  • Focus: Understanding the periodic table and matter interactions.

Basic Concepts

Matter

  • Definition: Anything with mass that takes up space.
  • Forms of Matter: Solid, Liquid, Gas.
  • Atoms: Basic unit of matter.
    • In class, atoms and elements are interchangeable.

Molecules and Compounds

  • Molecule: Two or more of the same atom bound together.
  • Compound: Two or more different atoms bound together (e.g., H2O).

Elements

Major Elements

  • Six Major Elements: Carbon, Hydrogen, Nitrogen, Oxygen, Phosphorus, Sulfur.
    • Make up 90-95% of living organisms.
    • Carbon and hydrogen are essential for organic molecules.

Minor Elements

  • Examples include sodium, potassium, calcium, iron, iodine, chlorine.

Atomic Structure

  • Protons: Positive charge, 1 atomic mass unit, in nucleus.
  • Neutrons: No charge, 1 atomic mass unit, in nucleus.
  • Electrons: Negative charge, 0 atomic mass units, in shells.
  • Nucleus: Center of atom where protons and neutrons are located.

Bonding

Ionic Bonds

  • Involves donation/acceptance of electrons (e.g., formation of NaCl).

Covalent Bonds

  • Non-polar: Equal sharing of electrons.
  • Polar: Unequal sharing of electrons (e.g., water).

Hydrogen Bonds

  • Between an electropositive hydrogen and an electronegative atom.

Properties of Water

  1. Polar Solvent: Dissolves substances like salt.
  2. Cohesive and Adhesive: Water binds to itself and other surfaces.
  3. High Surface Tension: Due to hydrogen bonds.
  4. High Heat Capacity: Takes a lot of energy to heat.
  5. High Heat of Vaporization: Requires breaking bonds to vaporize.
  6. Solid Water (Ice) is Less Dense: Ice floats on water.

Chemical Reactions

  • Reactants: Starting substances.
  • Products: Resulting substances.
  • Anabolic vs Catabolic: Builds vs breaks down.
  • Exergonic vs Endergonic: Releases vs requires energy.

Enzymes

  • Catalysts: Increase reaction speed by lowering activation energy.
  • Not Consumed: Reusable in reactions.
  • Enzyme Specificity: Specific to their substrates.

Enzyme Structures

  • Active Site: Where substrate binds.
  • Allosteric Site: Other binding site influencing enzymatic activity.

Factors Affecting Enzymes

  • Temperature: Optimal for enzyme activity.
  • pH: Optimal range necessary for enzyme activity.
  • Concentration: Saturation point of enzymes.

Acids, Bases, and pH

  • Acids: Release hydrogen ions (H+).
  • Bases: Release hydroxide ions (OH-).
  • pH Scale: Ranges from 1 (acidic) to 14 (alkaline), with 7 as neutral.

Macromolecules

Carbohydrates

  • Used for short-term energy and building blocks.
  • Monosaccharides: Simple sugars like glucose.
  • Disaccharides: Two sugars like sucrose.
  • Polysaccharides: Many sugars like glycogen.

Lipids

  • Simple Lipids: Fatty acids and glycerol.
    • Saturated Fats: No double bonds, solid at room temperature.
    • Unsaturated Fats: Have double bonds, liquid at room temperature.
    • Trans Fats: Unsaturated fat converted to saturated fat.
  • Complex Lipids: Include extra elements like phosphorus.
  • Steroids: Four-ring structure with a hydroxy group.

Proteins

  • Made of amino acids.
  • Functions: General cellular functions.

Nucleic Acids

  • DNA/RNA: Genetic material and protein synthesis.
  • Structure: 5-carbon sugar, phosphate, nitrogenous base.

ATP

  • Adenosine Triphosphate: Energy currency of the cell.
  • Conversion of ADP + inorganic phosphate with energy into ATP.

These notes cover the fundamental concepts discussed in the chemistry chapter, providing a comprehensive overview of the material covered in the lecture.