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Carboxylic Acid Reaction and Derivatives
Jul 20, 2024
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Mom's Lecture
Introduction
Today's lecture: Carboxylic Acid Reaction
Method of Preparation: Carbonyl Compounds
Formation of Aldehyde and Ketone from Alcohol
From 1┬░ alcohol: Aldehyde is formed
From 2┬░ alcohol: Ketone is formed
From 3┬░ alcohol: No reaction
Reagents: PCC, PDC, J&J, Cu + 830┬░C
Use of MnO2: Only Aldehyde production
Reaction
In properties of alcohol
: Alcohol oxidation
Formation of carbonyl from alkene
: By breaking bonds
Rosenmund Reductions
: With H2
Fehling's solution and Tollens' test
: Confirmation of aldehyde
Crossed Wing Reaction
Use of different reagents, 2 moles
Major product: Most stable compound
While making a table, note which is more reactive
Cannizzaro Reaction
Reaction of aldehyde without alpha-hydrogen with 50% NaOH
Cross Cannizzaro: Oxidation of one aldehyde and reduction of the other
Haloform Reaction
Methyl ketone or another type of difference
Reagents: Alkaline medium (NaOH), Iodine
Process by changing methyl ketone into halogen
Production: Haloform + and others
Exam-Oriented Questions and Answers
Practice from different sets of questions
Reagent-specific reactions
Study of oxidation and reduction reactions
Summary Notes
Note that most compounds can go through cross reactions
Emphasis on redox and oxidation in equations
Identification of nucleophilic addition reaction and their hydrolysis
Session Answers
Important questions and answers from the question paper
Examples of reactions and their identification
Highlights of reactions of various compounds
Motivational Quote
Message:
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