Transcript for:
Understanding Valence Bond Theory Essentials

valence bond theory in coordination chemistry in the topic putida individual anima pocket borough in the coordination chemistry ler in awareness theory crystal field theory in the market are they marry valence bond theory you in the coordination compounds a study upon a career or ethereal if earliness Pauling of being the scientist tada in the theory of proposed Pantera sila assumptions a base bunny outer the main assumption Ioannina this coordination compounds later a central metal atom Co Lagonda Kuna do Larry grey bond around it completely for a purely covalent of in solar array a diliman the bond when the yeah a primadonna in the central metal atom order vacant orbitals Oh Lagarde order filled orbitals Oh war lap a garden Allah in a bond when there would like they're being without solar right people on the on the assumptions the one by one I'm a patella so first orang asal resna central metal atom la central metal atom coldly turned the corner dual Erica bond when the covalent people in the central metal atom a beer Cana electron deficient darker upper yet turner ligands are the coup de banda Gerardo coordinator Caputo another other the coordination number other than a number of ligands than a coordination number so a thoroughly girls were though all other on the central metal at the third a coordination number yet then you're a ton of vacant orbitals other available of its Co second point when they ligand order orbitals under Nelligan or they are katha at least one orbital of it filled Arcana rather a lone pair of electrons vehicle under orbital layout so in the filled orbitals of Ataturk and ligands there and the electrons there the central metal atom could donate pon donate bunny Renda miss sharp an eco central metal atom o then league on do share panic Oh is there another cousin in the central metal atom a nap another yep Turner orbit was a vacant our Chico under orbitals firstly hybridize agate so hybridization takes place hybridization nanomaterial intermixing of orbitals of comparable or same energy as a mixer at the beragon could clear hybridized orbitals from the same energy our same number of same energy orbitals akuto coup by Hinda orbitals la perla gondolier ligand orbitals filled orbitals of the lagoon either one the overlap ow woven Apogee were born to create panel under bond coordinate covalent Sigma bond metal ligand coordinate metal ligand coordinate covalent Sigma bond coordinate covalent Sigma bond a formal Evo overlapping mother in the local cook under local and the bond when the stronger overlapping in the local Co the extent of overlapping energy on the bond or their vehicle strong argue if in the hybridized orbitals non directional hybridized orbitals no directional I I will call it geometry in space one day they have a particular geometry by the alarm on the inner inner sole align the valence bond Theory la inner orbitals complexes Rico outer orbital complex a circle inner orbital complexes na n minus one D orbitals now the N minus one D orbitals London hybridization they involve original other inner orbital complexes a PI n minus one D orbitals the upper hybridization lei involve a guna lagarde over the strongly gone dark llena strongly Grandville repel the electrons on the pair I'd a boy in the D orbitals love vacant orbitals Yuriko apart the hybridization involved ah go so PI R than all are the inner orbital complexes in row suppose were a weak ligand everything upon the pal electron pairing one another curve a PI electrons and pulled away D orbitals layer 3 D orbital slur and padavich oh so I per six ligands worried a of Dina or for regards were they Dina in the inner orbitals Levin the vacant orbitals your cousin so are the hybridization ly involve aagadu so automatic on the 3d kappa for is Capra for pick up rent of a four D for D orbitals involve ago so on the six ligands Vernon a six ligands qu6 hybridized orbitals familiar upper and the outer orbitals when the hybridization involve ago at the Nala the outer orbital complexes in SoLoMo about their orbital complexes yep our una Varela gondola the weak field ligand dark rapper upper the complex of Rico weak field ligand inner electron-pair America the Soviets about automatic on the electrons land pair desire cool apply electrons unpaired are in the channel and the complex they be up at a complex yes high spin complex so in the Darwin the valence bond Theory order important salad select features rumba is it on custome read you part of a silly example spots of none I'm okay nuclear up for you are indeed complexes a little ball octahedral complexes in at the pole wonder wonder Jeffy see and six three - first you get double say end up on a Perot valence bond theory are you spurning in the FE C + 6 3 - inter complex paramagnetic are in a diamagnetic are you later shape in you bring the factors a number power couple so first you on the namaka central metal atom we are in Pakenham so central metal atom ER a central metal atom ER in pagano sewing a central metal atom BR a right yeah fe de PFE and the configuration yes d6 configuration upend the configuration outer electronic configuration as a 3 d6 4s 2 3 D 6 4 s 2 if energy there in the central metal atom e fe in a theory of 3 D 6 for stool now the theory oh and I even the complex learn central metal hat the total charge in the day 3 3 in a 6-3 - so I learned it automatically Fe three-plus so in the metal atom could metal ion order configuration in a in the configuration let three electrons poitain above for Islam on the first is 0-2 electrons 23 dealer or electron poi 2 3 D 5 so in the Fe three-plus order the electronic configuration 3 D 5 4 is 0 if I the order orbital structure and a way you do there are orbital structure is aroun huh out there orbitals outer orbital in Aveiro about D orbital five bucks for know in a Phi orbiters 1 2 3 4 5 for SQL or orbital but 3 dealer fire electrons so 1 2 3 4 5 4 s like another 0 4 is 0 if o Yaran ligand and pecan Oerlikon did legardie are a.cian - where OC and the number students ponder over periodic peninnah in the cyanide in disorder percy and input oh yeah / coordination Spira with the editor or the metal at a market o ligand agate oh yeah per number and the coordination spear evety at the dimension but romo a pecan de patata charge a potent pasión - Percy and - from the arena either worried strong ligand strong field and yugandhar strong ligand strong field in the gun up in the strong field ligand every day multiple early on where the coordination number could remember six ligands or the motto six ligands worth this so even the iron and the Fe three-plus in a porno in the coordination number 6 that is 6 cyanide ligands lower this the kaga six vacant orbitals are available are my panel so in the presence of ligand the outer arbiters out there are beetles in the presence of ligand in now go in now go Lagaan in the presence of ligand in elegant er a cyanide ligand cyanide ligand opieop a telecon strong field ligand strong field ligand n upon oh yes electronic type or no so in the orbital na na the 3d orbital alia either 4s orbital find a electron 0 in your 5 electrons ok you pay in the presence of ligand as a strong ligand you nugget it in the electron gets add up of one to both on Jay Electronica 2 3 4 5 electrons an ID chain parrot snare plays our possible structure go up in the render orbitals golly RK in gora orbital golly okay you know it needs furthermore two orbitals partner for is caprile number four ohm novel neo-noir co 4 p orbital on our co 4 BR for p orbital moon orbital beeper 1 2 3 1 2 3 mother 6 orbitals vacant our K so 6 cyanide ligands kuru kuru electrons are under orbital an umbrella accommodate partner would eyoum so in the in the and electrons when the occupy ponder the community anger hybridization not a core so hybridize hybridized orbitals our hybridization you proven asana coordination number when this coordination number one then six a hybridization another kadai upper younger in given the day then is that in the new other d-league earns our key pipe on a poor orbitals na hybridized orbitals up on Abaddon upon Allah will cut paneer the tiny according I'm a political de carga number unity color upon the 3d fiber number later cut pond row pocket Panna in the moon orbital 3d a blue in the hybridized orbital in the 6 orbitals wanna hybridize idem 1 2 3 4 5 6 orbitals hybridized orbitals are here co-op I either Indian orbitals upper either in given the D when they're in their car a Purdy - yes wonder car yes P 1 2 3 number of orbitals the parka no at the power laborda no Munna Ditka numbers no number witted another photo confuse Panna cottas upper ended D orbital record D so rental car al Maleh to EDS orbital as an ally yes no or a royal alter King him a loved one L cannot talk you get P orbitals three-year Colonel of power let three Potter the moon Erica nombre the credit so six vacant orbital circle oh boy the six hybridized orbitals up a warrior PI the D 2 y SP 3 hybridised orbitals is a PI either on the electrons on the accommodate Nagano already in gear 1 2 3 4 5 electrons okay yep and Nirvana six cyanide ligands occur were or a cyanide llegando in gay electronic cuckoo oh no no b6 cyanide ligands the electrons are coda crapper and of overlapping na Dhin Dhin bond over the create ow upper one - or sign a Dorothy universally gnarly and our six sign it or a electrons running even though D do is P cube hybridized orbitals so coordination number when the $600 he's out of shape when this octahedral I'll together in the even there either orbitals Apocrypha were a moral single electron reckon but number of number of unpaired electrons number of unpaired electrons a tener que one a political magnetic moment in a magnetic moment in a magnetic behavior it is paramagnetic in nature by the magnetic moment enema calculate pet llama at the cusp in only moment have dinner for molecular mirrors is equal to root of Y n into n plus two very endless number of unpaired electron opinion pad electron owner K so 1 into 1 plus 2 root this is equal to root 3 which is equal to one point seven three two Bohr Magneton so a pre-work complex number valence bond Theory apply punny and the complex layer gender with Amana hybridization are accorded upon the ethanol unpaired electrons Rico under unpaired electrons a base pony or the paramagnetic are unpaired electrons Elena at a diamagnetic are being another determined / amarillo onion the ligand order nama considering that there you know this is whether it is strong field are weak field on it finally if it is ferromagnetic na Mohandas order magnetic moment an umbrella canterbury community home for a pie either one the number in their orbital complex out their orbital complex are known umbrella so aluminum if i inner orbital complex now yo in character actually an arena for Deever desire outer orbital and I either one dinamic II involve angular hybridization you know already in here 1 2 3 4 5 6 orbitals equal in the 6 orbitals local local area in the 3d 5 lyrical 2 D orbitals involve RK so n minus 1 D orbitals in the hybridization like involve RK so n minus 1 D orbital hybridisation they involve Allah and orbital occur and the complex inner orbital complex in pain so in the complex of Puerto Rico in the complex inner orbital complex repeat yenna inner orbital that is 3d orbital is involved in hybridization so you know a complex co nam la la' magnetic moment hybridization shape reality me at the inner orbital or outer orbit allah you know Russia angler valence bond Theory use funny number Allah candy / calculate pan Emilio even render complex as a either use funny come Parkin Amarillo for questions a prayer kana very complex a curiosity in the complex on the diamagnetic RK you know the complex circle 2:30 in the complex on the paramagnetic are yang Cara no I bring a questions Varela ya playin dollar sorry nomicon the metal at that order the electronic configuration theorem if I mean you could / shortcut now solar lunar we can have other people na mark in the 3d series learn another D block elements scandium Lorinda scandium know the zinc cover IQ metals vandal increasing of increasing order of atomic number a poet echo scandium khan the atomic number when the 21 whereas a zinc ago in the atomic number 30 mostly number teachers and lama and then in the you know and the easy on ya watch manganese Otani horas a special trick kalaiy azimuth Haven but when as far as students concerned how humble corrected Kalinda either yiyang yabba curriculum now or it recur prepare paneer tikka Adama this scandium Lorinda zinc or a keepo kappa game 2131 econ Tomic number increase oggi 10 elements 10 metals Vandalur come pay the only easier park I'm a political Tommy Laurel genetically another Joker krama rear comb but easier number two polymer nombre item video scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc zinc Boy Wonder 21 22 23 24 25 26 27 28 29 30 right either thou and their atomic numbers configuration putter d1 d2 d3 d4 d5 d6 d7 d 8 d 9 d 10 before either one they located on the D 400 D Phi I do Dean I know under D 10 Ida for stability yeah if on the d1 aware don't even crack solid D 1 and a 3 D 1 4 is 2 then I have thumb after then 3d to forest to titanium vanadium K 3 D 3 4 s to chromium kill 3 D 5 4 s 4 9 actual article 3d for force to the or a No and I in order to attain stability are in a panic Oh in the Marie other electronic configuration unico magnin iskele 3d 5 4 is to a bro I am good 3 D 6 4 s 2 COBOL ticket 3d 7 4 is 2 Nicola 3 D 8 4 s 2 copper could 3 D 9 forest tomorrow another 3 D 10 4 s 1 and L Co either want to attain stability da Prez inca 3d10 forest without the meaning number D 1 to D tendon where on D 1 to D or 10 portaloo actual electronic outer electronic configuration with this either though but you know only in the order bring our guts cuz they yeah bring above a chick Lavigne pata in the yes see di either one decide T V you see or Isetta wicker wicker where da we correct young man when the man said typical man yell yeah I want to govern the terrace offer cushion Reno I'm another panic be a thousand eleven uh para you remember ear ammonia feed on a Coney Coney not area you look circular cone Hyrum buco Neela corniness hotter than a year in Bologna let the spring cushion Senza rumble it's real and I'm a meaningless pocket bread pata in the marilla form pan away woody as so certainty Wicker Man II remember corn in the cushions in John 13 only yes yes CTA we crave easier man am and even by Fe corny Coco on the ceva cobalt nee na nickel a cushion see you is that an cushion lock ooh I don't see you is there another zinc in the marina Banja vivace club so you plea in either infinite pecan tree in Milan or a complex order magnetic behavior hybridization a magnetic moment in Latin America late Piniella