Atomic Mass and Isotopes Overview

Aug 19, 2025

Overview

This lecture explains what average atomic mass is, how it differs from mass number, and why a weighted average is used to represent atomic masses on the periodic table.

Atomic Number and Atomic Mass

  • The atomic number (top number) is the number of protons in an atom.
  • The number with decimals at the bottom of the periodic table is the average atomic mass, not the mass number.

Atomic Mass Unit (AMU)

  • Masses of individual atoms are extremely small when measured in grams.
  • Scientists use the atomic mass unit (AMU or amu) to express the mass of atoms.
  • One atomic mass unit is based on carbon-12.

Isotopes and Relative Abundance

  • Elements exist as mixtures of isotopes (atoms with same protons but different neutrons).
  • A typical sample contains different isotopes in different amounts (e.g., carbon-12, carbon-13, carbon-14).
  • Relative abundance is the percentage of each isotope in a sample (e.g., carbon-12 ≈ 98.89%, carbon-13 ≈ 1.1%).

Weighted Average Concept

  • Average atomic mass is a weighted average of all the naturally occurring isotopes.
  • Weighted average means more abundant isotopes contribute more to the average mass.
  • The calculation requires knowing each isotope’s mass and its relative abundance.

Mass Number vs. Actual Atomic Mass

  • Mass number is the total number of protons and neutrons in an isotope.
  • Actual atomic mass is measured in amu and is not always a whole number.

Key Terms & Definitions

  • Atomic Number — Number of protons in an atom.
  • Average Atomic Mass — The weighted average mass of all naturally occurring isotopes of an element.
  • Atomic Mass Unit (amu) — Unit for expressing atomic and molecular masses; based on carbon-12.
  • Isotope — Atoms of the same element with different numbers of neutrons.
  • Relative Abundance — Percentage of each isotope present in a natural sample.
  • Weighted Average — An average where each component contributes according to its proportion in the whole.
  • Mass Number — The total number of protons and neutrons in an atom’s nucleus.

Action Items / Next Steps

  • Watch the next video for detailed steps on calculating average atomic mass.