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Molecular Bonding and Structures

Jun 18, 2025

Overview

The lecture discusses the formation and properties of molecular elements and compounds, focusing on covalent bonding, Lewis dot diagrams, and examples of molecular structures.

Ionic vs Covalent Compounds

  • Ionic compounds form when atoms transfer electrons from one to another.
  • Covalent compounds form when atoms share electrons rather than transfer them.
  • Atoms sharing electrons are held together by covalent bonds, resulting in molecules.

Molecular Elements and Compounds

  • Molecular elements consist of the same kind of atom sharing electrons (e.g., Oโ‚‚, Sโ‚ˆ).
  • Molecular compounds consist of different kinds of atoms sharing electrons (e.g., Hโ‚‚O).
  • Only sharing electrons forms molecules; other interactions do not.

Properties of Molecular Substances

  • Molecular substances can be solids, liquids, or gases at room temperature.
  • They tend to have lower melting points than ionic compounds and metals.
  • Many molecular compounds have low solubility in water, but exceptions exist.
  • Molecular substances generally do not conduct electricity.

Covalent Bonding and Lewis Dot Diagrams

  • Covalent bonds are shared pairs of electrons between non-metal atoms.
  • Lewis dot diagrams help illustrate valence electrons and covalent bonding.
  • Non-metals typically share electrons to fill their outer shell (octet rule).

Examples of Covalent Bonding

  • In phosphorus trichloride (PClโ‚ƒ), phosphorus shares electrons with three chlorine atoms, forming three covalent bonds.
  • In oxygen gas (Oโ‚‚), each oxygen shares two pairs of electrons, resulting in a double bond.
  • In nitrogen gas (Nโ‚‚), each nitrogen shares three pairs of electrons, creating a triple bond.
  • Each shared pair of electrons is represented by a line in structural formulas.

Key Terms & Definitions

  • Ionic Compound โ€” a compound formed by the transfer of electrons.
  • Covalent Bond โ€” a chemical bond formed by sharing pairs of electrons.
  • Molecule โ€” a group of atoms bonded by covalent bonds.
  • Molecular Element โ€” a molecule made of only one type of atom.
  • Molecular Compound โ€” a molecule made of different types of atoms.
  • Lewis Dot Diagram โ€” a representation showing valence electrons as dots around atomic symbols.
  • Double Bond โ€” two shared pairs of electrons between two atoms.
  • Triple Bond โ€” three shared pairs of electrons between two atoms.

Action Items / Next Steps

  • Practice drawing Lewis dot diagrams for different molecular compounds.
  • Review the properties of ionic and covalent compounds.