Understanding Atom Models and Electron Behavior

Jul 15, 2024

Understanding Atom Models and Electron Behavior

Rutherford Model

  • Proposed by: Ernest Rutherford in 1909.
  • Description: Atom similar to a mini solar system.
    • High-density positive nucleus at the center.
    • Electrons orbit the nucleus at high speeds (negative charge).
  • Problem:
    • An orbiting electron has centripetal acceleration.
    • Accelerating electron radiates energy and loses it.
    • Using Larmora formula, electron would lose energy in ~10 picoseconds.
    • Electron would crash into the nucleus making atoms unstable.
    • Contradiction: Atoms are stable (real-world observation).

Standing Wave Model

  • Better Representation: Electrons as standing waves, not orbiting particles.
  • Explanation using metal ring:
    • Ring resonates at specific frequencies forming standing waves.
    • Discrete energy inputs allow standing waves.
    • Only certain wavelengths fit in the circle (integral number of wavelengths).
  • Niels Bohr's Proposal:
    • Electrons increase energy in discrete intervals (Quantum Leaps).
    • Energies are quantized (discrete packets).
    • Electrons move to different vibrations, not a smooth transition.

Orbital Visualization

  • Experiment analogy:
    • Metal ring shows resonant modes with various nodes.
    • Electrons display similar vibrational modes (known as orbitals).
  • Electron Behavior:
    • Electrons measured as particles, not spread out waves.
    • S orbital: Electron's first resonant frequency.
    • Measurement shows random electron locations, probabilistic nature.
    • Wave function: Probability distribution for electron locations.

Differences from Ring Model

  • Ring: Provides modes with an odd number of half wavelengths.
  • Bohr Model: Allows modes with even number of wavelengths.
    • Attachment to vibration apparatus causes disparity.

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