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Understanding Atom Models and Electron Behavior
Jul 15, 2024
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Understanding Atom Models and Electron Behavior
Rutherford Model
Proposed by
: Ernest Rutherford in 1909.
Description
: Atom similar to a mini solar system.
High-density positive nucleus at the center.
Electrons orbit the nucleus at high speeds (negative charge).
Problem
:
An orbiting electron has centripetal acceleration.
Accelerating electron radiates energy and loses it.
Using Larmora formula, electron would lose energy in ~10 picoseconds.
Electron would crash into the nucleus making atoms unstable.
Contradiction: Atoms are stable (real-world observation).
Standing Wave Model
Better Representation
: Electrons as standing waves, not orbiting particles.
Explanation using metal ring
:
Ring resonates at specific frequencies forming standing waves.
Discrete energy inputs allow standing waves.
Only certain wavelengths fit in the circle (integral number of wavelengths).
Niels Bohr's Proposal
:
Electrons increase energy in discrete intervals (Quantum Leaps).
Energies are quantized (discrete packets).
Electrons move to different vibrations, not a smooth transition.
Orbital Visualization
Experiment analogy
:
Metal ring shows resonant modes with various nodes.
Electrons display similar vibrational modes (known as orbitals).
Electron Behavior
:
Electrons measured as particles, not spread out waves.
S orbital
: Electron's first resonant frequency.
Measurement shows random electron locations, probabilistic nature.
Wave function
: Probability distribution for electron locations.
Differences from Ring Model
Ring
: Provides modes with an odd number of half wavelengths.
Bohr Model
: Allows modes with even number of wavelengths.
Attachment to vibration apparatus causes disparity.
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