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Avogadro's Constant and the Mole

Sep 12, 2025

Overview

This lecture introduces Avogadro's Constant and the mole as key units for counting particles in chemistry, relating them to real-world counting units and their significance for atomic and molecular mass calculations.

Units as Counting Tools

  • Everyday units like "pair" (2) and "dozen" (12) are used to count objects.
  • The mole is a counting unit in chemistry, representing a much larger number: 6.022 × 10²³ particles.

Avogadro's Constant and the Mole

  • Avogadro's Constant (6.022 × 10²³) is the number of particles in one mole of a substance.
  • The mole allows chemists to work with manageable quantities instead of individual atoms or molecules.

Mass and the Mole

  • The mass of one mole of an element (in grams) equals its atomic weight from the periodic table.
  • 1 mol of vanadium (V) = 6.022 × 10²³ atoms = 50.9415 grams.
  • 1 mol of magnesium (Mg) = 6.022 × 10²³ atoms = 24.305 grams.
  • Different elements have different molar masses, just as a dozen baseballs and a dozen softballs have different masses.

Compounds and Molecular Weight

  • For compounds, 1 mole = molecular weight in grams.
  • 1 mol of CO₂ = 6.022 × 10²³ molecules = 44.0 grams.
  • The distinction between atoms (elements) and molecules (compounds) is essential for understanding chemical reactions.

Key Terms & Definitions

  • Mole — A unit representing 6.022 × 10²³ particles (atoms, molecules, etc.).
  • Avogadro's Constant — The numerical value 6.022 × 10²³, representing the number of particles in a mole.
  • Atomic Weight — The mass (in grams) of one mole of an element's atoms, as listed on the periodic table.
  • Molecular Weight — The mass (in grams) of one mole of a compound's molecules.

Action Items / Next Steps

  • Review atomic and molecular weights on the periodic table.
  • Prepare for discussion on the distinction between atoms and molecules in the next lecture.