Central Metabolism and Energy Production

Jun 3, 2025

Metabolism and Its Central Pathways

Overview of Central Metabolism

  • Glucose is central to cellular metabolism.
  • Glycolysis: Glucose is converted to pyruvate through a series of enzyme-catalyzed reactions.
  • Krebs Cycle (Citric Acid Cycle): Pyruvate is converted to acetyl-CoA, which reacts with oxaloacetate to form citrate, entering a cycle of reactions to regenerate oxaloacetate.
  • Both glycolysis and the Krebs cycle are referred to as central metabolism as they are crucial for ATP production.

ATP Production

  • Central metabolism produces ATP, the cell's energy source.
  • Cofactors: NADH and FADH2 are produced, donating electrons to the electron transport chain to generate more ATP.

Variety of Metabolic Inputs

  • Monosaccharides: Other sugars like galactose can enter metabolism as intermediates.
  • Proteins and Amino Acids: Amino acids can enter metabolism after deamination (removal of nitrogen), forming alpha-keto acids.
  • Fatty Acids: Undergo beta-oxidation, forming NADH, FADH2, and acetyl-CoA.

Biosynthesis and Catabolism

  • Gluconeogenesis: Pyruvate can be converted back to glucose.
  • Amino Acids: Some amino acids can be converted into glucose precursors.
  • Fatty Acids: Generally cannot be converted into glucose but provide acetyl-CoA for other syntheses.

Energy Storage and Use

  • Fed State: Excess glucose and amino acids convert to triglycerides for storage.
  • Fasted State: Triglycerides are broken down to provide energy.

Specialized Metabolic Pathways

  • Ketogenesis: Acetyl-CoA in the liver forms ketone bodies as an energy source during fasting.
  • Cholesterol Synthesis: Acetyl-CoA can also contribute to cholesterol and steroid hormone synthesis.

Biosynthesis of Important Molecules

  • Amino Acids and Proteins: Central intermediates support the synthesis of non-essential amino acids.
  • Neurotransmitters: Dopamine, serotonin, and others are synthesized from metabolic intermediates.
  • Hemoglobin and Myoglobin: Formed from a porphyrin ring built from central metabolism intermediates.

Limitations of Central Metabolism

  • Vitamins and minerals cannot be synthesized through central metabolism and must be obtained from the diet.

Antioxidant Systems

  • Glutathione System: Reduces oxidative damage by neutralizing free radicals.

Complex Interconnections

  • Multiple pathways interconnect to sustain cell viability and function, proving central metabolism's importance.