Understanding Dilution Problems in Chemistry

May 14, 2025

Lecture Notes on Dilution Problems

Introduction

  • Topic: Solving dilution problems in chemistry.
  • Method Used: M1V1 = M2V2 formula, where:
    • M1 is the initial concentration (molarity)
    • V1 is the initial volume
    • M2 is the final concentration
    • V2 is the final volume

Problem 1: Sodium Chloride Solution

  • Problem Statement: 0.850 L of a 5.00 M solution of NaCl is diluted to 1.80 L. Find the concentration of the diluted solution.
  • Solution Steps:
    1. Use the equation M1V1 = M2V2.
    2. Solve for M2 (final concentration):
      • Rearrange to M2 = (M1 * V1) / V2.
    3. Plug in values:
      • M1 = 5.00 M
      • V1 = 0.850 L
      • V2 = 1.80 L
      • Calculate M2 = (5 * 0.850) / 1.80 = 2.36 M
  • Conclusion: The diluted concentration is 2.36 M, which is less than the initial concentration, indicating correct dilution.

Problem 2: Hydrochloric Acid Solution

  • Problem Statement: What volume of 0.12 M HCl can be prepared from 11 mL of a 0.45 M HCl stock solution?
  • Solution Steps:
    1. Use the equation M1V1 = M2V2.
    2. Solve for V2 (desired volume):
      • Rearrange to V2 = (M1 * V1) / M2.
    3. Plug in values:
      • M1 = 0.45 M
      • V1 = 11 mL
      • M2 = 0.12 M
      • Calculate V2 = (0.45 * 11) / 0.12 = 41 mL
  • Conclusion: The final volume required is 41 mL, which checks out as greater than the initial volume, indicating correct dilution.

Problem 3: Sodium Hydroxide Solution

  • Problem Statement: What volume of 1.59 M NaOH is required to prepare a 5.00 L solution of 0.1 M NaOH?
  • Solution Steps:
    1. Use the equation M1V1 = M2V2.
    2. Solve for V1 (volume of stock solution required):
      • Rearrange to V1 = (M2 * V2) / M1.
    3. Plug in values:
      • M2 = 0.1 M
      • V2 = 5.00 L
      • M1 = 1.59 M
      • Calculate V1 = (0.1 * 5) / 1.59 = 0.314 L
  • Conclusion: The volume of stock solution needed is 0.314 L, which is much smaller than the final volume needed, indicating correct dilution.

Conclusion

  • Key Takeaway: The dilution formula M1V1 = M2V2 is crucial for solving these types of problems in chemistry.
  • Additional Resource: For more detailed explanations, refer to the tutorial on solutions and dilution for further guidance.