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Understanding Concentration Units in Solutions

Mar 24, 2025

Lecture Notes: Concentration Units in Solutions

Overview

  • Discussion on various units used to measure concentration of solutions.
  • Learning objectives include defining concentration units and performing computations with them.

Learning Objectives

  • Define the concentration units:
    • Mass percentage
    • Volume percentage
    • Mass/Volume percentage
    • Parts per million (ppm)
    • Parts per billion (ppb)
  • Perform computations relating to solutions' concentration, components, volume, and mass.

Importance of Different Units

  • Chemists commonly use molarity but other fields use different units:
    • Mass percent: Common in consumer products (e.g., grocery, hardware store items).
    • Volume percent: Used in various applications.
    • Mass/Volume percent: Common in medicine.
    • Parts per million/billion: Used for measuring toxins in the environment.

Mass Percentage

  • Defined as the ratio of a component's mass to the solution's mass, expressed as a percentage.
  • Formula: (Mass of solute / Mass of solution) x 100
  • Used to describe solute concentrations; can also describe solvent concentrations.
  • Example: Liquid bleach has 7.4% sodium hypochlorite by mass.

Volume Percentage

  • Ratio of solute volume to solution volume, expressed as a percentage.
  • Formula: (Volume of solute / Volume of solution) x 100

Mass/Volume Percentage

  • Ratio of solute's mass to solution's volume, expressed as a percentage.
  • Common in saline solutions used in hospitals (e.g., 0.9% mass/volume sodium chloride solution).
  • Convenient for water solutions due to water's density being close to 1 g/mL.

Parts Per Million (ppm) and Parts Per Billion (ppb)

  • Used for very low solute concentrations.
  • ppm: (Mass of solute / Mass of solution) x 10^6
  • ppb: (Mass of solute / Mass of solution) x 10^9
  • Example: Trenton Waterworks report showed lead levels exceeding safe limits using ppb.
    • Action limit for lead: 15 ppb.
    • Lead is a cumulative toxin with no safe maximum level.
    • Source often from corrosion of household plumbing.
    • Example of application: Newark replaced plumbing lines due to similar issues.

Conclusion

  • Understanding different concentration units is crucial for various applications across fields such as consumer products, medicine, and environmental safety.