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Atomic Structure and Notation

Jun 10, 2025

Overview

This lecture explains atomic structure, chemical symbols, and how to determine atomic particles, isotopes, and ions using the periodic table.

Atomic Structure

  • Atoms are composed of three particles: protons (positive), neutrons (neutral), and electrons (negative).
  • John Dalton theorized that everything is made of atoms.
  • Protons and neutrons are located in the nucleus; electrons orbit the nucleus.

Chemical Symbols and Notation

  • A chemical symbol is written as ( ^A_ZX ), where X is the element, A is the mass number, and Z is the atomic number.
  • The atomic number (Z) equals the number of protons in the atom.
  • The mass number (A) equals the sum of protons and neutrons.

Atomic Mass vs. Mass Number

  • Mass number (A) is the total of protons and neutrons for a single atom.
  • Atomic mass is the weighted average of all isotopes of that element.

Determining Subatomic Particles

  • In neutral atoms, the number of protons equals the number of electrons.
  • Number of neutrons = mass number (A) minus atomic number (Z).
  • Protons and atomic number are always the same.

Ions and Their Charges

  • Ions are atoms with a net charge due to unequal protons and electrons.
  • Negative ions (anions) have more electrons than protons; positive ions (cations) have fewer electrons.
  • For a negative charge, electrons = protons + charge.
  • For a positive charge, electrons = protons - charge.

Examples and Problem Solving

  • For phosphorus (( ^{31}_{15}P^{3-} )), protons = 15, neutrons = 16, electrons = 18.
  • For phosphorus (( ^{31}_{15}P^{3+} )), protons = 15, neutrons = 16, electrons = 12.
  • Iron with 26 protons, 30 neutrons, and 29 electrons is an ion (( Fe^{3-} )), not neutral.

Determining Neutral vs. Ion

  • If protons = electrons, the atom is neutral.
  • If protons ≠ electrons, the atom is an ion.

Key Terms & Definitions

  • Atom — smallest unit of matter with unique chemical properties.
  • Proton — positively charged subatomic particle in the nucleus.
  • Neutron — neutral subatomic particle in the nucleus.
  • Electron — negatively charged subatomic particle orbiting the nucleus.
  • Atomic number (Z) — number of protons in an atom.
  • Mass number (A) — total number of protons and neutrons.
  • Atomic mass — average mass of all isotopes of an element.
  • Ion — atom with unequal numbers of protons and electrons, carrying a charge.
  • Isotope — atoms of the same element with different numbers of neutrons.

Action Items / Next Steps

  • Complete linked practice problems with step-by-step answers.
  • Leave questions or homework problems in the comments for help.