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Overview of Thermal Energy Transfers

Apr 27, 2025

HL IB Physics - Thermal Energy Transfers

Contents

  • Solids, Liquids & Gases
  • Density
  • Temperature Scales
  • Temperature & Kinetic Energy
  • Internal Energy
  • Thermal Equilibrium
  • Changes of State
  • Specific Heat Capacity
  • Specific Latent Heat
  • Thermal Conduction
  • Thermal Convection
  • Thermal Radiation
  • Apparent Brightness & Luminosity
  • Stefan-Boltzmann Law
  • Wiens Displacement Law

Solids, Liquids & Gases

  • States of Matter: solid, liquid, gas
  • Kinetic Theory: explains properties of matter
    • Particles as small spheres

Solids

  • Particles:
    • Closely packed
    • Arranged in fixed lattice
    • Vibrate in fixed positions
    • Low energies, can't overcome intermolecular forces
  • Properties:
    • Fixed shape and volume
    • High density, difficult to compress

Liquids

  • Particles:
    • Closely packed, randomly arranged
    • Flow past each other
    • Higher energy than solids
  • Properties:
    • No fixed shape, takes container's shape
    • Fixed volume, hard to compress
    • Medium density

Gases

  • Particles:
    • Far apart, random arrangement
    • Move freely and collide
    • High energy, can overcome intermolecular forces
  • Properties:
    • No fixed shape or volume, fills container
    • Compressible
    • Low density

Density

  • Definition: Mass per unit volume
  • Units: g/cm³ or kg/m³
  • Example: Bucket of feathers vs. sand
  • Calculations involve using volume formulas for shapes

Temperature Scales

  • Kelvin Scale:
    • Absolute zero: 0 K or -273 °C
    • Conversion: T(K) = T(°C) + 273
    • No negative values in Kelvin

Temperature & Kinetic Energy

  • Particles have diverse speeds
  • Average kinetic energy: (E_k = \frac{3}{2}k_BT)
    • (k): Boltzmann's constant (1.38 \times 10^{-23} J/K)
    • Proportionality to temperature

Internal Energy

  • Definition: Sum of total kinetic and intermolecular potential energy
  • With thermal energy change:
    • Increases kinetic and potential energy
    • Temperature change only with kinetic energy change

Thermal Equilibrium

  • Energy transfers from hotter to cooler region until equal temperature
  • No more heat exchange once equilibrium is reached

Changes of State

  • Phase transitions include melting, freezing, boiling, condensation
  • Energy Transfer: affects potential, not kinetic energy

Specific Heat Capacity

  • Definition: Thermal energy required to change 1 kg of substance by 1 K
  • Formula: (Q = mc\Delta T)
  • Substances like water have high specific heat capacities

Specific Latent Heat

  • Definition: Energy needed to change state of 1 kg without temperature change
  • Types:
    • Fusion: solid to liquid
    • Vaporisation: liquid to gas
  • Energy required for vaporisation > fusion

Thermal Conduction

  • Heat transfer in solids, more effective in metals due to free electrons
  • Involves atomic vibrations and electron collisions
  • Thermal Conductivity: Substance's ability to conduct heat
    • High in metals, low in insulators
    • Formula: (\frac{Q}{t} = \frac{kA\Delta T}{x})

Thermal Convection

  • Movement of fluids due to density changes
  • Occurs in liquids and gases, not solids
  • Creates convection currents

Thermal Radiation

  • Emission of electromagnetic waves, typically in infrared
  • Black-body Radiation: Perfect absorber/emitter
  • Heat transfer method in vacuum

Apparent Brightness & Luminosity

  • Apparent Brightness: Intensity from a star on Earth (b = \frac{L}{4\pi d^2})
  • Luminosity: Total power emitted by a star

Stefan-Boltzmann Law

  • Power radiated by black body: (P = \sigma AT^4)
  • Relates temperature and surface area to power emitted

Wiens Displacement Law

  • Peak wavelength inversely proportional to temperature (\lambda_{max} = \frac{b}{T})_

These notes provide a comprehensive overview of key points related to thermal energy transfers, useful as a study aid.