Reactivity Series of Metals

Jun 7, 2025

Overview

This lecture covers the reactivity series of metals, their reactions with acids and water, and how the reactivity series predicts displacement reactions.

The Reactivity Series of Metals

  • The reactivity series ranks metals by how easily they lose outer shell electrons to form positive ions.
  • Group 1 metals are the most reactive; group 2 are less reactive, and transition metals are generally the least reactive.
  • Carbon and hydrogen, though not metals, are included as reference points in the series.

Metal Reactions with Acids

  • Metals react with acids to produce a salt and hydrogen gas.
  • The reaction is most violent for highly reactive metals (e.g., potassium), becoming less vigorous down the series.
  • Copper typically does not react with acids.
  • Reactivity with acid can be measured by bubble production, disappearance of metal, or temperature change.
  • Use equal mass, surface area, and acid concentration to fairly compare metal reactivity.

Metal Reactions with Water

  • Reactive metals form a metal hydroxide and hydrogen when reacting with water.
  • Only the most reactive metals (like lithium) react readily with water; zinc, iron, and copper do not react at all.
  • Magnesium reacts very slightly with water.

Displacement Reactions

  • A more reactive metal can displace a less reactive metal from a compound in solution.
  • Example: Magnesium added to iron sulfate forms magnesium sulfate and iron.
  • A less reactive metal (like copper) cannot displace a more reactive metal (like iron) from its compound.

Key Terms & Definitions

  • Reactivity series — a list ranking metals by how easily they form positive ions.
  • Displacement reaction — a reaction where a more reactive element replaces a less reactive one in a compound.
  • Metal hydroxide — a compound formed when a metal reacts with water.
  • Salt — a compound formed from the reaction of an acid with a metal.

Action Items / Next Steps

  • Review examples of metals reacting with acids and water.
  • Practice predicting products of displacement reactions using the reactivity series.