Understanding Atomic Structure and Bonding

Aug 30, 2024

Lecture Notes: Atomic Structure and Chemical Bonds

Introduction

  • Overview of exam one practice exam for chemistry.
  • Focus on atomic structure, chemical bonds, and isotopes.

Atomic Structure

Subatomic Particles

  • Protons: Positive charge, determine the element.
  • Neutrons: No charge, affect the isotope.
  • Electrons: Negative charge, affect reactivity.

Atoms and Ions

  • Atoms are electrically neutral when protons = electrons.
  • Ions: Formed by changing the number of electrons.
  • Isotopes: Formed by changing the number of neutrons.

Atomic Number and Mass

  • Atomic Number: Number of protons in an atom, determines the element.
  • Atomic Mass: Total number of protons and neutrons.
  • Atomic Weight: Average mass of all isotopes of an element.

Chemical Bonds

Types of Bonds

  • Covalent Bonds: Sharing of electrons between atoms.
    • Polar Covalent Bonds: Unequal sharing (e.g., water).
    • Non-Polar Covalent Bonds: Equal sharing (e.g., O2, H2).
  • Ionic Bonds: Transfer of electrons between atoms (e.g., NaCl).

Bond Properties

  • Electronegativity: Tendency of an atom to attract shared electrons.
  • Hydrogen Bonds: Weak bonds between polar molecules, responsible for water's unique properties.
  • Van der Waals Forces: Weakest interactions between molecules.

Elements in Biological Systems

  • Most common elements: Hydrogen, Carbon, Oxygen, Nitrogen.
  • Properties: Low atomic mass, not necessarily full outer shells.

Chemical Reactions and Interactions

  • Hydrogen Bonds in Water: Responsible for cohesion and surface tension.
  • Like Dissolves Like: Polar substances dissolve in polar solvents; non-polar in non-polar.

Practice Problems and Concepts

Distinguishing Elements and Isotopes

  • Different elements have different numbers of protons.
  • Isotopes have the same number of protons but different neutrons.

Ionic and Covalent Characteristics

  • Formation of ions and ionic bonds from electron transfer.
  • Formation of covalent bonds from electron sharing.

Exam Preparation Tips

  • Understand concept relationships (e.g., subatomic particles' roles, bond types).
  • Practice calculations for atomic mass and isotopes.
  • Familiarize with periodic table layout (atomic number, weight).

Key Takeaways

  • Protons determine element identity; neutrons affect isotope.
  • Electrons influence chemical behavior and bond formation.
  • Polar and non-polar covalent bonds defined by electronegativity.
  • Water's properties largely due to hydrogen bonding.

Conclusion

  • Thorough understanding of atomic structure and chemical bonds foundational for chemistry.
  • Review key concepts and practice problems for a comprehensive understanding.