Rules for Naming Hydrocarbons

Nov 9, 2024

Rules for Naming Hydrocarbons in Organic Chemistry

Introduction

  • Organic chemistry consists of various compounds that are often difficult to remember by name.
  • The video explains the basic rules for naming carbon compounds.

Naming Format

  • Like human names, the name of compounds also follows a format: Prefix, Root Word, Suffix.

Root Word

  • It depends on the number of carbon atoms present in the longest chain.
  • Examples:
    • 4 carbons: But
    • 3 carbons: Prop
  • It's important to remember this chart.

Prefix and Suffix

  • Prefix: Comes before the root word.
  • Suffix: Comes after the root word.
  • Functional groups are divided into low and high priority.
    • Use low priority in prefix and high priority in suffix.

Naming Rules

Rule 1: Identify the Longest Carbon Chain

  • First, identify the longest carbon chain for naming.
  • Examples:
    • 5 carbons: Root word = Pent
    • 3 carbons: Root word = Prop

Rule 2: Number the Carbon Atoms

  • Number the chain in an order with the lowest possible numbers.
  • Examples:
    • Numbering from Left: Correct
    • Numbering from Right: Incorrect
  • Correct name: 1-bromo-pentane-3-ol

Rule 3: Write the Name with Appropriate Prefix and Suffix

  • Write prefix and suffix with their positions in the numbering.
  • Examples:
    • 1-bromo-pentane-3-ol
    • Primary Suffix: Single bond = ane
    • Secondary Suffix: Position of functional group

Examples

  1. Described Compound: 2 carbons

    • Root word: Eth
    • Prefix: 1-bromo
    • Final name: 1-bromo-ethane
  2. Second Compound: 4 carbons, Double bond

    • Root word: But
    • Primary Suffix: in
    • Final name: But-2-ene
  3. Final Compound: 4 carbons, Functional groups (Chlorine, Aldehyde)

    • Root word: But
    • Prefix: 2-chloro
    • Final name: 2-chloro-butanal

Important Tips

  • IUPAC naming is a vast topic, this is enough for Class 9 and 10.
  • Take screenshots to remember as notes.
  • Keep the video and notes safe; they will work as foundation in Class 11 and 12.
  • More complex compound names will be learned later.

Share your questions or doubts in the comment section.