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Ionic Compounds and Lattices

Jun 15, 2025

Overview

This lecture explains how ionic compounds form giant ionic lattices, their high melting and boiling points, and their electrical conductivity properties.

Formation of Ionic Compounds

  • Ionic bonding occurs when a metal reacts with a non-metal, transferring electrons from metal to non-metal.
  • The metal becomes a positive ion (cation), and the non-metal becomes a negative ion (anion).
  • Both resulting ions achieve a stable, full outer electron shell similar to noble gases.
  • Example: Sodium reacts with chlorine to form sodium chloride (NaCl).

Giant Ionic Lattice Structure

  • Ionic compounds form giant three-dimensional structures called giant ionic lattices.
  • In a giant ionic lattice, every positive ion is surrounded by negative ions and vice versa.
  • Strong electrostatic (ionic) forces of attraction hold ions in place, and these forces act in all directions.
  • These strong forces are referred to as ionic bonds.

Properties of Ionic Compounds

  • Ionic compounds have high melting and boiling points due to strong electrostatic forces requiring a lot of heat energy to break.
  • Example: Sodium chloride has a melting point around 800°C.
  • Ionic compounds do not conduct electricity in the solid state because ions are locked in place and cannot move.
  • When molten or dissolved in water, ions are free to move and carry electrical charge, allowing the compound to conduct electricity.
  • In ionic conduction, it is the movement of ions (not electrons) that carries the charge.

Key Terms & Definitions

  • Ionic Bond — Electrostatic force of attraction between oppositely charged ions.
  • Giant Ionic Lattice — A large, regular, three-dimensional arrangement of ions in an ionic compound.
  • Cation — A positively charged ion.
  • Anion — A negatively charged ion.

Action Items / Next Steps

  • Review and practice questions on ionic compounds and their properties from the revision workbook.