🧪

Overview of Period 3 Elements in Chemistry

Mar 17, 2025

Notes on Period 3 Elements - AQA Chemistry A-level

Properties of Period 3 Metals

  • Sodium and Magnesium
    • React ionically to form positive ions.
    • Sodium: Forms 1+ ions, more reactive due to requiring less energy to ionize (loses one electron).
    • Magnesium: Forms 2+ ions, less reactive as it requires losing two electrons.
    • Reaction speed increases with steam, resulting in a violent reaction with magnesium burning with a bright white flame, producing hydrogen and magnesium oxide.

Period 3 Oxides

  • Elements react with oxygen to form oxides in their highest oxidation state (usually the same as group number).
  • Sulfur can form SO₃ with oxidation state +6 (requires high temperatures and a catalyst).

Oxides Table:

OxideStructure & BondingMelting Point (°C)Reactivity
Na₂OIonic1250Vigorous
MgOIonic2750Vigorous
Al₂O₃Ionic/covalent2000Slow (faster if powdered)
SiO₂Macromolecular1500Slow
P₄O₁₀Simple covalent500Vigorous
SO₂Simple covalent-10Burns steadily

Reactions with Water

  • Ionic Oxides: Combine with water to form alkaline solutions (pH 10-14).
  • Covalent Oxides (Sulfur and Phosphorus): Combine with water to form acidic solutions (pH 0-2).
    • In solution, these acids dissociate into H⁺ ions and ions of conjugate base.

Acid-base Reactions

  • Basic, Ionic Oxides: React with acids to produce a salt and water (neutralization reaction).
  • Acidic, Covalent Oxides: React with bases to produce a salt and water (neutralization reaction).

Amphoteric Nature of Aluminium Oxide

  • Partially ionic and covalent bonding.
  • Insoluble in water as ions don't dissociate.
  • Acts as both acid and base, known as amphoteric.
    • Participates in neutralization reactions to form salt and water.