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1.3 Introduction to Macromolecules

Sep 6, 2025

Overview

This lecture introduces macromolecules, focusing on the processes of building and breaking down polymers—dehydration synthesis and hydrolysis—vital concepts for understanding biological molecules in living organisms.

What Are Macromolecules?

  • Macromolecules are large biological molecules made primarily of carbon, hydrogen, oxygen, nitrogen, phosphorus, and sulfur.
  • The main biological macromolecules are carbohydrates, proteins, lipids, and nucleic acids.
  • Macromolecules consist of smaller subunits called monomers linked together to form polymers.

Monomers vs. Polymers

  • A monomer is a small molecule that can bind to others to form a polymer.
  • A polymer is a large molecule made by joining many monomers via covalent bonds.
  • Dimer refers to a molecule made from two monomers.

Importance in Living Things

  • Living things require intake of carbon-based molecules (food) from their environment.
  • Food is broken down and rearranged to build the molecules needed by cells.
  • The breakdown and rebuilding of these molecules is part of metabolism.

Hydrolysis

  • Hydrolysis is the process of breaking down polymers into monomers.
  • In hydrolysis, water is added to break covalent bonds between monomers.
  • One monomer receives a hydrogen ion (H), and the other receives a hydroxyl group (OH) from the water molecule.
  • This reaction requires the help of enzymes.

Dehydration Synthesis

  • Dehydration synthesis is the process of joining monomers to form polymers.
  • An H from one monomer and an OH from another are removed to form a water molecule, allowing a new covalent bond between the monomers.
  • Multiple dehydration synthesis reactions create long polymers (polymerization).

Summary & Key Points

  • Food polymers must be broken down to monomers via hydrolysis before being rebuilt into new polymers by dehydration synthesis.
  • Hydrolysis and dehydration synthesis are opposite reactions crucial for metabolism.

Key Terms & Definitions

  • Macromolecule — a large molecule made of smaller subunits.
  • Polymer — a large molecule made of repeating monomers.
  • Monomer — a small subunit that can join others to form a polymer.
  • Hydrolysis — reaction that breaks polymers into monomers using water.
  • Dehydration Synthesis — reaction that joins monomers to make polymers by removing water.
  • Polymerization — process of linking many monomers to form a polymer.
  • Enzyme — a protein that speeds up chemical reactions (covered more in Unit 3).

Action Items / Next Steps

  • Review definitions of monomer, polymer, hydrolysis, and dehydration synthesis.
  • Prepare for the next lesson on carbohydrates.