Understanding Valence Electrons and Reactivity

Aug 14, 2024

Lecture Notes: Determining Valence Electrons in Main Group Elements

Introduction

  • Focus on determining valence electrons for elements in the main groups.
  • Main groups are classified using the one through eight system.
  • Groups 3 through 12 are ignored in this context.
  • Valence electrons are those in the outermost shell.

Determining Valence Electrons

  • Valence electrons can be determined by the group number for main group elements.

Sodium Example

  • Electron Configuration for Sodium:
    • 1s² 2s² 2p⁶ 3s¹
  • Valence Electrons in Sodium:
    • Sodium has one valence electron in the third energy level.
    • Sodium is in group 1, which corresponds to its one valence electron.

Chlorine Example

  • Electron Configuration for Chlorine:
    • 1s² 2s² 2p⁶ 3s² 3p⁵
  • Valence Electrons in Chlorine:
    • Chlorine has seven valence electrons in the third energy level.
    • Chlorine is in group 7, which corresponds to its seven valence electrons.

Reaction of Sodium and Chlorine

  • Sodium loses one electron:
    • Becomes a sodium cation (Na⁺) with a stable electron configuration like neon.
  • Chlorine gains one electron:
    • Becomes a chloride anion (Cl⁻) with a stable electron configuration like argon.
  • Ionic Bond Formation:
    • Attraction between Na⁺ and Cl⁻ forms an ionic bond.

Reactivity of Groups

  • Group 1 (Alkali Metals):
    • Highly reactive due to having one valence electron.
  • Group 7 (Halogens):
    • Highly reactive as gaining one electron gives them a noble gas configuration.
  • General Rule:
    • Group number equals number of valence electrons for main group elements.

Additional Example: Oxygen

  • Oxygen Group:
    • Group 6, so oxygen has six valence electrons.

Conclusion

  • Understanding electron configurations and valence electrons explains the reactivity of elements.
  • Main group elements' reactivity is linked to their desire to achieve stable electron configurations similar to noble gases.