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Quantum Mechanical Model of Atoms: Electron Configuration

May 28, 2024

Quantum Mechanical Model of Atoms: Electron Configuration

Introduction

Presenter: Iman Platform: YouTube Series: High Yield MCAT General Chemistry Video: #7 Topic: Electron Configuration (Part Two)

Key Concepts

Electron Configuration

  • Definition: Distribution of an atom's electrons among various orbitals.
  • Basis: Quantum mechanical principles.
  • Importance: Explains arrangement of electrons within an atom.

Principles Governing Electron Configuration

  1. Aufbau Principle:

    • Electrons fill orbitals starting from the lowest energy level to higher energy levels.
    • Example: 1s orbital fills before 2s orbital.
    • Visual representation: Periodic table order of elements.
  2. Pauli Exclusion Principle:

    • Each orbital can hold a maximum of 2 electrons with opposite spins.
    • No two electrons can have the same set of all four quantum numbers.
  3. Hund’s Rule:

    • Electrons fill degenerate (equal energy) orbitals first before pairing up.
    • Minimizes electron-electron repulsion and is energetically favorable.

Writing Electron Configurations

  • Critical Skill: Helpful for chemists and MCAT preparation.
  • Energy Levels: Increase generally with the principal quantum number (n).
    • Example: 3d orbitals have higher energy than 4s orbitals despite '4' being a larger number than '3'.
  • Simplified Order: Can be derived from the periodic table.
    • S, D, P, and F orbitals are read based on periodic table locations.

Example: Carbon (C)

  • Position: Identify Carbon's location on the periodic table.
  • **Configuration Steps: **
    1. 1s2: Fill the 1s orbital.
    2. 2s2: Fill the 2s orbital.
    3. 2p2: Move to the 2p orbital and fill 2 boxes.
  • Result: Electron configuration for Carbon = 1s2 2s2 2p2.

Conclusion

  • Review: Periodic table as a tool for electron configurations.
  • Practice: Writing configurations for different elements.
  • Encouragement: Good luck, happy studying, and best wishes to future doctors!

Questions and Comments Welcome!