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Understanding Amphoteric Behavior of Alumina

May 6, 2025

Chemistry Lesson: Amphoteric Behavior of Alumina (Unit 5)

Introduction

  • Lesson Focus: Amphoteric behavior of alumina
  • BTEC Applied Science Unit 5
  • Learning Aim: A1 (Looking at amphoteric behavior)
  • Future lesson will cover metal oxides and hydroxides

Key Definitions

Acid

  • Definition: Substance that dissociates in water to form H⁺ ions
  • Examples:
    • HCl (Hydrochloric acid): Dissociates to H⁺ and Cl⁻
    • H₂SO₄ (Sulfuric acid): Releases two H⁺ and sulfate ion (SO₄²⁻)
  • Types:
    • Monoprotic Acid: Releases 1 H⁺ (e.g., HCl)
    • Diprotic Acid: Releases 2 H⁺ (e.g., H₂SO₄)

Base

  • Definition: Reacts with acids to form salt and water
  • Distinction:
    • Alkali: A base that dissolves in water to form OH⁻ ions
    • Note: All alkalis are bases, but not all bases are alkalis

Amphoteric

  • Definition: Substance that can act as both an acid and a base
  • Example: Alumina (Aluminium oxide)

Alumina (Aluminium Oxide)

Chemical Properties

  • Formula: Al₂O₃
  • Composition:
    • Aluminium (Al): Group 3, forms 3⁺ ions
    • Oxygen (O): Group 6, forms 2⁻ ions
  • Inertness: Chemically inert (unreactive except with hot acids or bases)

Amphoteric Behavior

  • Reactions:
    • With Acids:
      • Example reaction with HCl (Hydrochloric Acid) or H⁺
      • Simplified to show reaction with H⁺
    • With Bases (Hydroxides):
      • Different reactions based on conditions (e.g., hot vs. not hot hydroxides)
      • Know one sample reaction for exams

Uses of Alumina

  • Applications:
    • Fillers in paints, sunscreens, glasses
    • Chromatography (e.g., thin layer chromatography)
    • Effective desiccant (drying agent)
  • Notes: Desiccants used in products like shoe boxes to remove moisture

Conclusion

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  • Next Topic: Metal oxides and hydroxides