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Understanding Naming Ionic and Molecular Compounds

May 28, 2025

Naming Ionic and Molecular Compounds

Introduction

  • Instructor: Melissa Maribel
  • Focus: Understanding naming of ionic and molecular (covalent) compounds
  • Importance: Essential for chemistry studies; naming compounds is a frequent task

Identifying Compound Types

  • Ionic Compounds: Consist of one metal and one nonmetal
    • Generally, metals have positive charges and nonmetals have negative charges
  • Molecular (Covalent) Compounds: Consist of two nonmetals

Ionic Compounds Naming

Without Transition Metals

  • Example: Aluminum Oxide (Al₂O₃)
    • Metal name + Nonmetal name ending in "ide"
    • Balance charges: Aluminum (3+), Oxygen (2-)
    • Use subscripts to balance charges
    • "Lasso" method: Swap and balance opposite charges

With Transition Metals

  • Example: Iron (III) Oxide (Fe₂O₃)
    • Name includes metal, Roman numeral (indicating metal's charge), nonmetal ending in "ide"
    • Example: Iron (3+), Oxygen (2-)
    • Balance charges with subscripts to reach neutrality

With Polyatomic Ions

  • Example: Calcium Phosphate
    • Metal + Polyatomic ion name
    • Polyatomic ions often end in "ate" or "ite" (exceptions include hydroxide and cyanide)
    • Balance charges (Calcium 2+, Phosphate 3-)
    • Use parentheses for polyatomic ions and subscript

Transition Metals with Polyatomic Ions

  • Example: Copper (II) Nitrate
    • Transition metal name with Roman numeral + Polyatomic ion
    • Copper (2+), Nitrate (NO₃ with -1 charge)
    • Balance charges with subscripts

Naming from Formulas

  • Example: FeBr₂
    • Identify elements: Fe (Iron, transition metal), Br (Bromine, nonmetal)
    • Use Roman numeral for transition metal: Iron (II) Bromide
  • Example: Cu₃(PO₄)₂
    • Copper (transition metal) + Phosphate (polyatomic ion)
    • Copper (2+) and polyatomic ion charges help determine naming: Copper (II) Phosphate

Molecular (Covalent) Compounds Naming

  • Prefixes: Know 1-10 (mono-, di-, tri-, etc.)
  • Formula: Prefix + Nonmetal name + Prefix + Nonmetal name ending in "ide"
  • Example: Diphosphorus Pentoxide
    • Subscripts determine prefixes (Di=2, Pent=5)
  • Example: N₃O₆
    • Trinitrogen Hexaoxide

Conclusion

  • Practice naming compounds and balancing charges
  • Resources: Online tutoring available
  • Encouragement: You can learn anything you set your mind to