Lecture on Nuclear Waste and Recycling
Key Points
- Nuclear Waste Overview:
- Most nuclear fuel rods still contain over 90% of their energy when discarded.
- Up to 96% of spent nuclear fuel is recyclable.
- Few countries actively recycle nuclear waste.
France's Nuclear Recycling
- France's Recycling Plant:
- Operated by Orano, located in western France.
- France: highest share of nuclear power globally (two-thirds of electricity from nuclear).
- All spent nuclear fuel in France is transported to this plant for recycling.
- The plant features 24,000 rooms, two-thirds of which are underground.
- Daily handling of 110-ton transportation casks containing nuclear waste.
Steps in Nuclear Recycling
- Fuel Rod Removal:
- Fuel rods are removed from transportation casks in sealed chambers using remote machinery.
- Control room operation.
- Cooling:
- Fuel rods are stored in cooling pools for 5-7 years.
- Pools contain baskets with nuclear fuels submerged under four meters of water.
- Disassembly and Separation:
- Chemical process: separation of uranium, plutonium, and fission products.
- Metal cladding separated from fuel pellets.
- Dissolved in nitric acid, then solvent extraction for uranium and plutonium.
- Remaining fission products are non-recyclable.
- Vitrification:
- Trapping fission products in glass and storing them.
- Reduces storage space required.
Plutonium and Safety Concerns
- Plutonium Handling:
- Plutonium can be used for nuclear weapons (e.g., India in the 1970s).
- Orano uses MOX fuel (mixing plutonium with uranium), reducing fresh uranium use by 30%.
- MOX fuel accounts for 10% of France's electricity.
- Transportation of plutonium involves high-security measures.
Cost and Global Practices
- Economic Aspects:
- Recycling is expensive due to specialized facilities and processes.
- Mining fresh uranium is currently cheaper.
- France recycles more than it can reuse; excess recycled uranium is stored.
- Recycling does not eliminate the need for long-term waste storage.
- Global Practices:
- Russia, India, and China are expanding recycling capacities.
- UK ceased recycling due to high costs.
- Experimental methods (e.g., pyroprocessing) are still in lab phases.
- Strategic Choice:
- France sees recycling as maintaining energy sovereignty, supported by state-owned operations.
- Future nuclear technologies and economic shifts may change viability.
Conclusion
- Recycling Nuclear Waste:
- Not universally feasible due to economic and technical challenges.
- Countries like France, Russia, and China are exceptions due to strategic decisions.
- Long-term storage solutions still required for nuclear waste.
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