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Fundamentals of Chemistry Problem Solving

May 24, 2025

Lecture on Basic Concepts of Chemistry and Problem Solving

Instructor Introduction

  • Instructor: Bhagan K Patel
  • Subject: Chemistry
  • Focus: KCT Examination preparation

Key Topics Discussed

Law of Multiple Proportions

  • Two oxides of a metal produce different amounts of water upon reaction.
    • Ratio of water produced: 0.2g and 0.4g.
    • Results: 1:2 ratio, illustrating the Law of Multiple Proportions.

Mole Calculations at STP

  • Hydrogen Gas Example:
    • 22.4 L of hydrogen gas contains 1 mole.
    • 2.24 L contains 0.1 mole.
    • Discrepancy in statement about moles; correct statement involves molecules, not moles.

Molecules in Compounds

  • Aluminum Sulfate Example:
    • Molar mass of Al2(SO4)3ยท18H2O = 666 g/mol.
    • Calculating water molecules in a given mass.

Liquid Volume and Gas Density

  • NO2 Example:
    • 224 mL of NO2 liquified with density of 2.2 g/mL.
    • Calculate volume and number of molecules in liquid.

Equal Volume, Equal Molecules

  • 500 mL Gas Comparison:
    • At STP, equal volumes mean equal number of molecules for different gases.

Moles and Molecules in Water

  • 1800g Water Example:
    • 18g of H2O = 1 mole = Avogadro's number of molecules.
    • 1800g contains 100 moles.

Chemical Reaction Stoichiometry

  • HCl and MnO2 Reaction:
    • Calculate grams of HCl needed to react with 5g MnO2.

Atomic and Molecular Weights

  • Compound AB2 Example:
    • Calculate molecular weight using atomic weights and moles.

Conservation of Mass

  • Example:
    • 36g Carbon + 32g Oxygen = 68g CO2.

Constant Proportions in Compounds

  • Calcium Carbonate Example:
    • Determine carbon weight in a specific sample using percentage composition.

Ratio and Proportion

  • Helium Atoms Example:
    • Unified mass calculations to find number of atoms in a sample.

Comparing Molecular Weights

  • Weight Comparison:
    • Use given weights and calculate equivalents to find order.

Oxygen Consumption in Reactions

  • Comparison:
    • Determine minimum oxygen consumption per gram of reactant.

Correct and Incorrect Statements

  • Chemical Laws:
    • Reviewing accuracy of statements regarding atomic mass, molecular mass, and laws of combination.

Molarity and Density Calculations

  • H2SO4 Solution Example:
    • Calculate molarity given density and weight percentage.

Isotope Mass and Abundance

  • Argon Isotopes:
    • Calculate molar mass using isotope abundance.

PPM Calculations

  • Sodium Chloride Solution Example:
    • Convert percentage weight/volume to PPM using specific gravity.

Closing Remarks

  • Reminder for students to practice problems regularly.
  • Encouragement to prepare well for examinations.

These notes summarize the key problem-solving strategies and concepts discussed in the lecture, providing a foundational understanding for chemistry students preparing for exams.