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Key Concepts in Modern Atomic Physics

Apr 23, 2025

Modern Physics Lecture Notes

Introduction to Modern Physics

  • Modern physics is often taught at the end of the physics syllabus.
  • Topics include atomic physics, important for JEE Main and NEET.
  • Atomic structure is essential for understanding atoms and is interconnected with chemistry.

Atomic Physics Overview

  • Focus on atomic structure to grasp deeper concepts beyond chemistry.
  • The course will cover key points from JEE Main to JEE Advanced levels.
  • Students should prepare a checklist with previous year questions.

Key Models of Atomic Structure

  1. Thomson's Model

    • Described atom as a spherical ball with positive charge spread uniformly and electrons distributed like seeds in a watermelon.
    • No nucleus concept; it explained neutral behavior of atoms.
  2. Rutherford's Model

    • Based on alpha particle scattering experiment on gold foil.
    • Discovered nucleus; electrons orbit around a dense, positively charged nucleus.
    • Predicted that electrons radiate energy and spiral into the nucleus, a limitation of this model.
  3. Bohr's Model

    • Addressed Rutherford's limitations through three postulates.
    • Explained stable electron orbits without energy loss.
    • Introduced quantized orbits where electrons can only exist in specific energy levels.

Bohr's Atomic Model

Postulates of Bohr's Model

  1. First Postulate

    • Electrons revolve around the nucleus in a stable orbit without radiating energy.
    • Force from nuclear charge provides centripetal force for circular motion.
  2. Second Postulate

    • Electrons can only occupy quantized orbits, defined by quantized angular momentum:
      mv_r = n(h/2π)
    • Angular momentum must be integral multiple of h/2π.
  3. Third Postulate

    • Energy is emitted when electrons transition between orbits. The energy emitted corresponds to the difference between the two orbits:
      E = E_n2 - E_n1 = hν = hc/λ

Properties of Electrons in Bohr Model

  • Radius of nth orbit:
    R_n = (n^2h^2)/(4π^2kZ)
  • Velocity of electron in nth orbit:
    v_n = (2πkZ)/(nh)
  • Angular velocity:
    ω_n ∝ Z^2/n^3
  • Time period of revolution:
    T_n ∝ n^3/Z^2
  • Current due to revolving electron:
    I_n ∝ Z^2/n^3
  • Magnetic moment of nth orbit:
    μ_n = (eh)/(4πm)
  • Energy of electron in nth orbit:
    E_n = -13.6 eV * (Z^2/n^2)*

Energy Levels and Spectral Series

  • Energy levels become closely spaced as n increases.
  • Excitation and Ionization:
    • Excitation: Transition from a lower to a higher energy level.
    • Ionization: Energy required to remove an electron entirely from the atom.

Frequency and Wavelength of Emitted Radiation

  • Emission occurs when an electron transitions from a higher to lower energy level.
  • Rydberg's Formula:
    1/λ = RZ^2(1/n1^2 - 1/n2^2)
  • Energy and wavelength relations:
    E = hc/λ

Atomic Collisions

  • Collisions can supply energy for excitation or ionization.
  • The impact parameter determines how much energy is transferred to the electron.
  • Collisions can result in a range of energies being transferred.

Conclusion

  • Understanding these concepts is essential for solving problems in JEE and NEET.
  • Prepare a detailed checklist based on these notes and previous year questions for revision.
  • Emphasize on grasping concepts to solve problems efficiently.