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Chemical Bond Types and Electron Roles

Jun 8, 2025

Overview

This lecture explains different types of chemical bonds between atoms—ionic and covalent—and how electrons determine bonding behaviors and molecular structure.

Types of Chemical Bonds

  • Atoms bond to other atoms of the same or different elements to form compounds.
  • An ionic bond forms when one atom transfers electrons to another, creating oppositely charged ions that attract each other.
  • Sodium chloride (table salt) is held together by ionic bonds, forming a 3D lattice.
  • A covalent bond forms when atoms share pairs of electrons between them.
  • Proteins and DNA are primarily held together by covalent bonds.

Electron Arrangement and Bonding

  • Atoms are electrically neutral with equal numbers of protons and electrons.
  • Only outermost electrons ("valence electrons") in the highest energy orbitals are involved in bonding.
  • In ionic bonding, transferred electrons come from the outermost orbital of the donating atom.
  • In covalent bonding, shared electrons also come from the outermost orbitals.

Bonding Capacity of Common Elements

  • Carbon has four valence electrons and typically forms four covalent bonds.
  • Nitrogen has three valence electrons and typically forms three bonds.
  • Oxygen has two valence electrons and usually forms two bonds.
  • Hydrogen has one valence electron and forms only one bond.
  • Occasionally, atoms can form more bonds than usual under special circumstances.

Molecules and Molecular Size

  • Molecules are groups of atoms connected by covalent bonds.
  • Molecules can be small, like two oxygen atoms forming O₂, or extremely large, such as human chromosome 13 with billions of atoms.
  • Chemical bonds are fundamental in holding atoms together in these structures.

Key Terms & Definitions

  • Ionic bond — attraction between oppositely charged ions formed by electron transfer.
  • Covalent bond — attraction between atoms that share pairs of electrons.
  • Valence electrons — electrons in the outermost orbital involved in bonding.
  • Lattice — 3D grid-like arrangement of ions in an ionic compound.
  • Molecule — a group of atoms held together by covalent bonds.

Action Items / Next Steps

  • Review the definitions and examples of ionic and covalent bonds.
  • Practice identifying types of bonds in sample compounds.
  • Prepare for a quiz on electron arrangement and bonding capacity of key elements.