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Protein Types and Structures

Sep 2, 2025

Overview

This lecture explains the two main types of proteins—globular and fibrous—highlighting their structures, properties, functions, and key examples relevant for Cambridge A Level Biology.

Types of Proteins

  • Proteins are divided into two main classes: globular proteins and fibrous proteins.
  • Globular proteins are generally spherical and water-soluble.
  • Fibrous proteins are elongated, insoluble, and provide structural support.

Differences in Polypeptide Chains

  • Polypeptide chains with mainly hydrophilic (water-attracting) amino acids tend to form globular proteins.
  • Chains with mostly hydrophobic (water-repelling) amino acids form fibrous proteins.
  • In water, globular proteins fold so hydrophilic amino acids face outwards, making them soluble.
  • Fibrous proteins do not dissolve in water and maintain a fiber-like shape.

Globular Proteins

  • Water-soluble due to exposed hydrophilic amino acids.
  • Spherical (not circular) in shape—must use "spherical" or "ball-shaped" in exams.
  • Participate in chemical reactions (e.g., act as enzymes, transporters like hemoglobin, or antibodies).
  • Mobility in watery environments allows globular proteins to perform metabolic functions.

Fibrous Proteins

  • Water-insoluble, unaffected by water.
  • Provide structural roles (e.g., keratin in hair/nails, collagen in skin/blood vessels, elastin in airways).
  • Do not participate in chemical reactions due to insolubility and structure.

Example: Hemoglobin (Globular Protein)

  • Hemoglobin is a protein found in red blood cells, not the cell itself.
  • Composed of two α (alpha) and two β (beta) polypeptide chains, each with a different primary structure.
  • Chains fold into secondary (alpha helix), tertiary, and then quaternary structures.
  • Each polypeptide includes a heme group (non-protein, contains iron, binds oxygen).
  • Hemoglobin is classified as a quaternary protein due to its four interacting chains.

Example: Collagen (Fibrous Protein)

  • Collagen consists of three polypeptide chains forming a triple helix (quaternary structure).
  • Every third amino acid in collagen is glycine, the smallest amino acid, allowing tight coiling.
  • Multiple collagen molecules connect with staggered covalent cross-links to form collagen fibrils.
  • Staggered cross-links provide strength, flexibility, and resistance to breaking.
  • Collagen fibers have high tensile strength and are important in skin, tendons, and artery walls.

Key Terms & Definitions

  • Globular Protein — Spherical, water-soluble protein involved in metabolic reactions.
  • Fibrous Protein — Insoluble, elongated protein providing structural support.
  • Hydrophilic Amino Acid — Amino acid that interacts with water (polar).
  • Hydrophobic Amino Acid — Amino acid that avoids water (non-polar).
  • Quaternary Structure — Protein structure with two or more polypeptide chains interacting.
  • Hemoglobin — Oxygen-binding globular protein in red blood cells.
  • Collagen — Structural fibrous protein with triple-helix structure and high tensile strength.
  • Heme Group — Non-protein component of hemoglobin that binds oxygen.
  • Glycine — The smallest amino acid, critical for tight coiling in collagen.

Action Items / Next Steps

  • Review and memorize the structural and functional differences between globular and fibrous proteins.
  • Learn the details of hemoglobin and collagen structures for upcoming chapters.
  • Ensure clear understanding of key terms, especially quaternary structure and the role of glycine in collagen.