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Cosmetic Chemistry Overview

Jun 19, 2025

Overview

This lecture covers the principles of cosmetic chemistry, types of mixtures and emulsions, skincare products, functional and performance ingredients, and regulatory considerations relevant to estheticians.

Cosmetic Mixtures & Classifications

  • Most skincare products are mixtures of two or more substances.
  • Solutions are mixtures where substances are evenly dispersed and mixable.
  • A solvent dissolves another substance (solute).
  • Immiscible mixtures involve molecules that cannot be mixed.
  • Products requiring shaking before use are suspensions.
  • Suspensions separate when left standing.
  • Liquid foundation is classified as an emulsion.
  • Soaps are fats and oils converted to fatty acids by heat and purification.
  • Powders must be sifted until free of coarse particles.
  • Ointments are mixtures of organic substances and medicinal agents.

Emulsions & Delivery

  • Emulsions are two or more immiscible substances united with a binder.
  • Examples of emulsions: mayonnaise, cold cream.
  • Oil-in-water is a common cosmetic emulsion (e.g., moisturizing lotions).
  • Most industry emulsions are oil-in-water type.
  • The solute is the powder mix in Kool-Aid.
  • A saturated solution cannot dissolve more solute at a given temperature.
  • The non-polar end of an emulsifier is lipophilic (oil-loving, water-hating).

Skincare Products & Routines

  • Cleansing removes dirt, oil, makeup, and pollutants from the skin.
  • Use oil-free makeup remover for clients with false eyelashes.
  • Toners cleanse further and balance skin pH; fresheners have the lowest alcohol content.
  • Exfoliation removes dead skin; physical (granular scrub) or chemical (enzymes/AHAs).
  • Lotions are moisturizers with high water content and light consistency.

Sun Protection

  • Sun exposure is the main cause of skin cancer and premature aging.
  • SPF is based on UVB rays.
  • Physical sunscreens reflect UV rays (e.g., zinc oxide, titanium dioxide).
  • Broad spectrum sunscreen protects against UVA and UVB.
  • Chemical sunscreens include oxybenzone, avobenzone, and octinoxate.

Masks, Treatments & Special Care

  • Clay masks absorb excess oil and refine pores.
  • Peel-off masks lock in moisture and tighten skin.
  • Paraffin masks are used for hand and face, but do not absorb oil.
  • Gel masks soothe sensitive skin.
  • Organically grown ingredients are free from pesticides and GMOs.

Ingredients & Labeling

  • Delivery systems (liposomes, microsponges, hydrogels) control ingredient release.
  • Water is typically the first ingredient on product labels due to its weight.
  • Humectants hold water in the skin.
  • Emulsifiers are compatible with oil and water.
  • Surfactants (cleansing agents) remove oil and dirt.
  • Emollients prevent moisture loss.
  • Preservatives protect against bacteria and extend product life.
  • Colorants enhance product appearance.
  • pH adjusters alter product acidity/alkalinity.
  • Fragrances mask raw ingredient odors.
  • Hypoallergenic means less likely to cause allergies.
  • Performance ingredients produce the intended effect.

Product Safety & Regulation

  • Non-comedogenic ingredients do not clog pores.
  • Over-the-counter (OTC) products are sold without a prescription.
  • Antibacterial ingredients destroy acne-causing bacteria.
  • Ingredients are listed on labels by descending concentration.
  • FDA regulates cosmetics in the U.S.

Key Terms & Definitions

  • Emulsion — a mixture of two immiscible substances held together by a binder.
  • Surfactant — a cleansing agent that removes oil and dirt.
  • Humectant — ingredient that retains moisture in the skin.
  • Broad Spectrum — sunscreen that blocks both UVA and UVB rays.
  • Hypoallergenic — less likely to cause allergic reactions.
  • Non-comedogenic — does not clog pores.

Action Items / Next Steps

  • Review product labels and identify functional and performance ingredients.
  • Read assigned chapter on cosmetic chemistry and regulations.
  • Prepare to discuss skincare routines and ingredient functions in next class.