Naming Covalent Molecular Compounds Guide

Feb 19, 2025

Naming Covalent Molecular Compounds

Distinguishing Molecular and Ionic Compounds

  • Molecular Compounds: Typically composed of two nonmetals.
  • Ionic Compounds: Composed of a metal and a nonmetal. Example: MgCl₂ (Magnesium Chloride).
  • Example of Molecular Compound: SCl₂ (Sulfur Dichloride).
  • Prefixes: Used in molecular compounds, not in ionic compounds.

Common Prefixes

  • Mono: 1 (not used for the first element)
  • Di: 2
  • Tri: 3
  • Tetra: 4
  • Penta: 5
  • Hexa: 6
  • Hepta: 7
  • Octa: 8
  • Nona: 9
  • Deca: 10

Naming Rules for Molecular Compounds

  • First Element: Name as is (without prefix "mono" if one atom).
  • Second Element: Use prefix for number of atoms and suffix "-ide".

Examples

  1. CO

    • Name: Carbon Monoxide
  2. CO₂

    • Name: Carbon Dioxide
  3. NO₂

    • Name: Nitrogen Dioxide
  4. N₂O₅

    • Name: Dinitrogen Pentoxide
  5. NO

    • Name: Nitrogen Monoxide
  6. N₂O₃

    • Name: Dinitrogen Trioxide

More Practice Examples

  1. PCl₃

    • Name: Phosphorus Trichloride
  2. PCl₅

    • Name: Phosphorus Pentachloride
  3. CBr₄

    • Name: Carbon Tetrabromide
  4. OF₂

    • Name: Oxygen Difluoride
  5. SiF₄

    • Name: Silicon Tetrafluoride
  6. SF₆

    • Name: Sulfur Hexafluoride
  7. IF₇

    • Name: Iodine Heptafluoride
  8. P₄O₁₀

    • Name: Tetraphosphorus Decooxide (omit "a" in decaoxide)

Tips

  • Electronegativity: The more electronegative element in a compound is given the "-ide" suffix.
  • Trends: Electronegativity increases towards fluorine on the periodic table.

Conclusion

  • Apply learned prefixes and naming rules to identify and name covalent molecular compounds accurately.
  • Upcoming video will cover writing formulas for molecular compounds.

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