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Naming Covalent Molecular Compounds Guide
Feb 19, 2025
Naming Covalent Molecular Compounds
Distinguishing Molecular and Ionic Compounds
Molecular Compounds
: Typically composed of two nonmetals.
Ionic Compounds
: Composed of a metal and a nonmetal. Example: MgCl₂ (Magnesium Chloride).
Example of Molecular Compound
: SCl₂ (Sulfur Dichloride).
Prefixes
: Used in molecular compounds, not in ionic compounds.
Common Prefixes
Mono
: 1 (not used for the first element)
Di
: 2
Tri
: 3
Tetra
: 4
Penta
: 5
Hexa
: 6
Hepta
: 7
Octa
: 8
Nona
: 9
Deca
: 10
Naming Rules for Molecular Compounds
First Element
: Name as is (without prefix "mono" if one atom).
Second Element
: Use prefix for number of atoms and suffix "-ide".
Examples
CO
Name: Carbon Monoxide
CO₂
Name: Carbon Dioxide
NO₂
Name: Nitrogen Dioxide
N₂O₅
Name: Dinitrogen Pentoxide
NO
Name: Nitrogen Monoxide
N₂O₃
Name: Dinitrogen Trioxide
More Practice Examples
PCl₃
Name: Phosphorus Trichloride
PCl₅
Name: Phosphorus Pentachloride
CBr₄
Name: Carbon Tetrabromide
OF₂
Name: Oxygen Difluoride
SiF₄
Name: Silicon Tetrafluoride
SF₆
Name: Sulfur Hexafluoride
IF₇
Name: Iodine Heptafluoride
P₄O₁₀
Name: Tetraphosphorus Decooxide (omit "a" in decaoxide)
Tips
Electronegativity
: The more electronegative element in a compound is given the "-ide" suffix.
Trends
: Electronegativity increases towards fluorine on the periodic table.
Conclusion
Apply learned prefixes and naming rules to identify and name covalent molecular compounds accurately.
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