⚗️

Understanding Chemical Reaction Rates

May 30, 2025

AQA GCSE Chemistry Topic 6: The Rate and Extent of Chemical Change

Rate of Reaction

  • Definition: Rate of reaction can be expressed by:
    • Rate of reaction = amount of reactant used / time
    • Rate of reaction = amount of product formed / time
  • Measurement:
    • Quantity can be measured by mass (grams) or volume (cm³).
    • Units of rate: g/s, cm³/s, or mol/s (using moles instead of mass or volume).

Graphical Analysis

  • Rates can be determined graphically by:
    • Drawing tangents to curves and using the slope of the tangent.
    • Calculating the gradient of a tangent on the graph to measure rate at a specific time.

Factors Affecting Reaction Rates

  • Factors:
    • Concentration
    • Pressure
    • Surface area
    • Temperature
    • Catalysts

Collision Theory and Activation Energy

  • Collision Theory:
    • Reactions occur when particles collide with sufficient energy.
  • Activation Energy:
    • Minimum energy required for particles to react.
  • Increasing Factors:
    • Higher concentration, pressure, and surface area increase collision frequency, thus increasing reaction rate.
    • Higher temperature increases collision frequency and energy, accelerating reaction rate.

Catalysts

  • Function: Speed up reactions without being consumed.
  • Biological Catalysts: Enzymes act as catalysts in biological systems.
  • Characteristics:
    • Not part of the chemical equation.
    • Decrease activation energy, increasing the proportion of particles with sufficient energy to react.
    • Provide an alternative reaction pathway with lower activation energy.

Note: Content in bold is specifically for Higher Tier studies.

Source: Physics and Maths Tutor