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Globular Proteins and Hemoglobin

Sep 13, 2025

Overview

This lecture introduces globular proteins, focusing on their structural features, water solubility, and how the structure of hemoglobin relates to its oxygen-carrying function.

Features of Globular Proteins

  • Globular proteins have an approximately spherical shape.
  • They are soluble in water due to hydrophilic (water-attracting) amino acids on their surface.
  • Hydrophilic R groups interact with water molecules, allowing solubility.
  • Hydrophobic (water-repelling) amino acids are buried in the center of the protein, away from water.

Types of Proteins

  • Proteins are broadly divided into globular and fibrous types based on structure.
  • This lecture focuses on globular proteins.

Structure and Function of Hemoglobin

  • Hemoglobin is a globular protein found in red blood cells.
  • It is composed of four polypeptide subunits: two alpha and two beta.
  • Hemoglobin's function is to bind and transport oxygen in the blood.
  • Each subunit contains a heme prosthetic group, making hemoglobin a conjugated protein.
  • Each heme group contains an Fe²⁺ ion where oxygen binds.
  • A single hemoglobin molecule can bind up to four oxygen molecules.
  • Binding oxygen induces a change in hemoglobin’s quaternary structure, making it easier for additional oxygen to bind.

Key Terms & Definitions

  • Globular protein — Protein with a compact, spherical shape, often soluble in water.
  • Hydrophilic — Attracted to water; describes R groups that interact with water molecules.
  • Hydrophobic — Repelled by water; describes R groups that avoid water.
  • Prosthetic group — Non-protein component tightly attached to a protein (e.g., heme group).
  • Conjugated protein — Protein containing a prosthetic group.
  • Quaternary structure — Protein structure formed by multiple polypeptide subunits.

Action Items / Next Steps

  • Review structures and functions of insulin and an enzyme in the next video.
  • Be able to explain how the structure of each globular protein relates to its function.