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Electron Configurations and Aufbau Principle

Sep 18, 2025

Overview

Explains how to write electron configurations using the aufbau principle and the periodic table.

Writing Electron Configurations

  • Electrons fill atomic orbitals from lowest to highest energy.
  • Each subshell is filled before moving to the next higher one.
  • The aufbau principle ("build up" in German) guides the order: start at 1s, then 2s, 2p, 3s, 3p, 4s, 3d, 4p, etc.

Using the Periodic Table

  • Each row (period) represents a shell (principal quantum number, n).
  • s-block: groups 1 and 2; p-block: right side; d-block: transition metals; f-block: lanthanides and actinides.
  • s and p blocks match the period number for n; d is one behind; f is two behind.

Applying the Aufbau Principle

  • Fill orbitals by reading the periodic table left to right, top to bottom.
  • Typical order: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, etc.
  • Use the periodic table or orbital diagrams to remember the order.

Key Terms & Definitions

  • Electron Configuration: Arrangement of electrons in orbitals.
  • Aufbau Principle: Electrons fill lowest energy orbitals first.
  • Subshell: Group of orbitals (s, p, d, f).
  • Principal Quantum Number (n): Main energy level.

Action Items / Next Steps

  • Practice writing electron configurations using the periodic table and aufbau principle.
  • Memorize how period numbers relate to s, p, d, and f orbitals.