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Chemical Percentage Composition

Jun 9, 2025

Overview

This lecture covers how to determine the percentage composition of a compound using its chemical formula or experimental mass data, an important skill for chemical analysis.

Percentage Composition Concept

  • Percentage composition expresses the proportion by mass of each element in a compound.
  • It is calculated as (mass of element in compound / total molar mass of compound) Ă— 100%.
  • Knowing percentage composition helps in finding empirical formulas in advanced studies.

Calculating from Chemical Formula

  • Identify the elements present in the compound and their atomic masses from the periodic table.
  • Count the number of atoms of each element in the chemical formula.
  • Calculate the compound's total molar mass by summing the masses of all atoms present.
  • Use the formula: (mass of element in one mole / molar mass of compound) Ă— 100%.
  • Example: For HCl (hydrochloric acid), hydrogen is 2.74% and chlorine is 97.26% by mass.

Calculating from Mass Data

  • Record the mass of the whole compound and the mass of each element present.
  • If one element’s mass is unknown, subtract known element(s) from the total mass to find it.
  • Calculate each element’s percentage using (mass of element / total compound mass) Ă— 100%.
  • Example: In a 30g sample with 24.12g zinc, Zn is 80.40% and O is 19.60% by mass.

Key Terms & Definitions

  • Percentage Composition — the percent by mass of each element in a compound.
  • Molar Mass — the mass of one mole of a compound, calculated from atomic masses.
  • Empirical Formula — the simplest whole-number ratio of elements in a compound.

Action Items / Next Steps

  • Practice calculating percentage composition from both chemical formulas and mass data.
  • Review atomic masses on the periodic table for future calculations.