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Limiting Reagents in Chemistry

Sep 6, 2025

Overview

This lesson introduces the concept of limiting reagents in stoichiometry, using recipes and balanced equations to determine which reactant limits the amount of product formed.

Everyday Analogy for Limiting Reagents

  • A recipe (e.g., baking a cake) has specific ratios of ingredients needed (e.g., 2 eggs + 1 teaspoon flour = 1 cake).
  • If you have extra of one ingredient but not enough of the other, the ingredient in short supply limits how much product you can make.
  • The limiting reagent is the ingredient that runs out first and stops the reaction (or baking) from continuing.

Applying Limiting Reagents to Chemistry

  • In chemical equations, reactants must be mixed in certain ratios, like recipe ingredients.
  • You are given amounts of two reactants (e.g., nitrogen and hydrogen) and must determine which will be used up first.
  • The limiting reagent determines how much product can be formed; the other reactant is left in excess.

Method for Finding the Limiting Reagent

  • Use the balanced equation to identify the required molar ratio (e.g., Nโ‚‚ + 3Hโ‚‚ โ†’ 2NHโ‚ƒ means 1:3 ratio).
  • Choose one reactant and calculate how much of the other is needed to react completely using the stoichiometric ratio.
  • Compare the calculated amount needed to the actual amount present.
  • The reactant that is present in a smaller quantity than required is the limiting reagent.

Practice with Ratios and Examples

  • For awkward ratios (e.g., 3:5 or 2:7), multiply the given amount by the ratio needed to determine required amounts.
  • Always "times by" (multiply) using (needed/available) to compare and determine the limiting reagent.
  • The limiting reagent is consistently found by this method, regardless of which reactant is considered first.

Key Terms & Definitions

  • Stoichiometry โ€” Calculation of reactant and product quantities in chemical reactions.
  • Limiting Reagent โ€” The reactant that is completely consumed first, limiting the amount of product formed.
  • Excess Reagent โ€” The reactant that remains after the reaction is complete.
  • Balanced Equation โ€” Chemical equation with equal numbers of each atom on both sides, dictating the reaction ratios.
  • Molar Ratio โ€” Proportion of moles of one substance to another as indicated by a balanced equation.

Action Items / Next Steps

  • Practice determining the limiting reagent using various balanced chemical equations and ratios.
  • Review previous notes on stoichiometry and ensure understanding of balanced equations.
  • Prepare for next lesson, which will build upon the concept of limiting reagents.