Transcript for:
Organic Chemistry Foundations

General organic chemistry is a simple but It is considered an important topic because In further organic chemistry its No story, no application for you It appears that if between these two two electrons are being shared which that we already know, so in such a case electrons A will take its electron and run away from the carbon will take its electron and run away, which will be called a Intermediate consideration will be given and this The intermediate will be named as free radical between carbon and chlorine the electron cloud is on the chlorine side have to lean a little more because Negativity of chlorine and more halo Kids how are you everyone's mind map Another organic important in the series We are again in front of you with the chapter Date has come in this general organic chemistry Considered a simple but important topic It goes because the whole organic There is no story behind this in chemistry If you do not see any application then I think it is General Organic Chemistry. whose name itself has revealed a lot today General organic chemistry means you are a Discussing Organai History next to which there is a Nishan story na story, you must definitely show it to me If you give it then we will do this general organic chemistry The point which is raised first in the discussion of If we talk about his elder brother then What I think in this brief discussion all that can be done is that we First off for the big talking g's What kind of take off for will be seen in organic chemistry Date is formality of network live Bound cleavage then we effects some We will talk about electronic effects like Inductive effect has become resonance effect Is it done or is it hyper conjugation effect After that some hum and resonating Rules for writing structures and their Stability can never be compared to that of a bar There will be some attempt to compare it We will talk about hyper conifers in detail will plus its applications in big will also be discussed and after that some special effects that occur within organic compounds which can be seen in their molecular properties governed by the Steering Animation of Resonance and Steering in mission of pro position or benoi acid or inside some sulfonic acid which is ortho Its effects are seen in the larger We will discuss some compounds Aromatic and non aromatic or non aromatic How the characters will be decided If we discuss it in bigger format then I have portions though you puri this again and again Story or no story in organic chemistry If it keeps showing then children will be able to see it well This is understandable too, but still the act List some basic terms that are used in organic He has his discussions in chemistry Chapters of this General Organic Chemistry I am already done with the story, mother Suppose you read carboxylic acid Started it and there was a term added that Brother carboxylic acid which is acidic There is strength, it is more than the final now carboxylic acid acidic acid is this Give more acidic final explanation to this if so, we already have some effects for it It is said that brother, this is acidic There is an effect inside the acid which This is called the resonance effect, which is aquino Forming energy resonating structures And there is resonance effect inside phenols too So after removing the hae, a child was born who phenoxides have come resonating Structures will be built but they are so He is not contributing that much You will not stabilize it with phenol phenoxide ion meaning my food There are many such things to see in the future You get these whose continuous application requires you to this organic chemistry general organic The application of chemistry keeps you constantly If we get to see it, we will first start We do Born relates things to cleavage And it is a very simple discussion Homolytic and Hadquality Brown Close If we talk about cleavage then You understand everything in organic chemistry Generally the bond cleavages would be If it is of any element adjacent to carbon then If I choose any one of the elements adjacent to carbon This mother, if I am late then she is with me who is closed Cleavage is power in all forms So a clavis for homeopathic There are also references to homolytic This comes in such a big closed cleavage we are talking about the electronic distribution is after closed cleavage and Closed Fusion lets you run electronic The distribution will look very similar That is, eating means that if these two There is sharing of two electrons between is happening which we already know, so in such a situation Electron A takes its electron part carbon will take its electron and run away will go and in such a situation whatever new situation you The front will be formed that carbon will be its own will separate itself from the rest by taking one electron which will be considered as an intermediate and This intermediate was named free radical this is free radical means one thing It is clear in organic chemistry whenever also homolytic cleavage will occur then a An intermediate will be formed which you can call a free radical. I will say another thing, this was also possible that the bond that is formed with carbon and A The sharing of two electrons between the two one man should take both the electrons This is absolutely possible, date depends on D electronegativity difference i.e. if in Both have electron negativity The difference is there so this can happen Now let one person take both the electrons If these two electrons are put into one man If it is late then two possibilities are divided into one The possibility is that if these two If electron A is applied then in such a case carbon So it will remain that you took mine with you too Then a positive charge will be applied on me and one because carbon also takes an electron ran away so the negative charge on A and in such a case the Intermediate It will be formed and you will name it Carbohydrate this is carbo cut it in some place The carbonium ion is also given by this carbonium ion let's say okay that is if If heterolytic cleavage occurs then In hydrolytic cleavage if A is taken from the carbon is more electronegative, so Electronus Lake will run away and in such a situation If a positive charge appears on carbon then a A new intermediate will be created which will be called Caborketyan will be given another possibility what is the third possibility The possibility is that with carbon and a The sharing of two electrons in the cage those two electrons should be taken by the man who which is carbon i.e. if both of these If electrons take carbon then this is what happens In your new intermediate which is made in A negative charge appears on the carbon and A positive charge comes on top, so this The intermediate was named as carbanion goes this It is clear that homo and heterosexuality are cleavages If you talk about big things then one thing It seems quite clear that this is Cleavage is the cleavage of homeopathy because both people have their own electrons ran away with it but this cleavage if Let us look at the story in organic chemistry If so, this is known as heterolytic cleavage A will know it is a very simple thing yes As far as the conditions are concerned, they are gradually improving. We will do very much but still each and every general The idea can be taken that if I If I talk about conditions then homology The major conditions I have for having cleavage Hi, the first condition that has come in it Temperature must be mentioned, that is, either high temperature will be mentioned or a in condition The presence of photons will be kept on this date Presence of sunlight can cause photons The presence of such a form is like the power to be kept also has the power to say that we have a nonpolar solvent There seems to be a possibility of this as well, i.e. if Even if the solvent is non-polar, it is still homeopathic clinics seem to have potential and the fourth The condition is if the radical initiator Even if there is presence you should consult homeopathic doctor. will be seen because if the radical initiator del If you go, there are chances of you becoming a radical will be given a bigger one i.e. radical initiator too We can find radicals in the question Initiators may also be provided to you in the question Are And The most common example of a radical initiator is is that we know dat is peroxide even if there is presence of To you I can see homeopathic leaves well nonpolar n situation so okay but if you talk about cleavage Which condition can be seen then This is the only thing for electrolyte cleavage it is called electron negativity Difference plays a big role in this there is no doubt and the second condition is that if Even if you are maintaining low temperature, there are chances there are chances of having cleavage and thirdly if you are polar Even if we talk about solvent, there are chances Having the image of a hydro leader is created i.e. Eating means that if I am normal If I talk about the situation then homeopathic leaves And there is one thing about heterosexual cleavage Homeopathy is clearly visible Electronic Distribution Similar in hoga and hetal electronic distribution date will have both electrons either one did it seem like a man or another man in such a case 99 Intermediate will be formed that file article in it and how did the caborcetian do carbonaceous now if I go further So this is what I understand that brother you did your intermediate like this stability comparing this or to govern molecular properties for some permanent inside some molecules These are the effects that are bothering me You just have to observe them permanently If we talk about the effects, then the The first effect that comes is inductive The effect is quite clear from the name Sigma Electronic Distribution is one of those You can see the movement of sigma electrons I will see and observe you electronegativity difference i.e. of food This means that if I talk straight I will do an effect that I don't know about It may or may not be true, but I do know this that this effect is going on in this molecule I'll have to observe it myself This means that eating carbon and Negativity of Chlorine in Chlorine Carbon It is a very good caste, in such a situation it It is clear that the lions of carbon and chlorine Electrons means this sigma These are the sigma electrons will shift towards chlorine due to which Chlorine will get a negative charge and this Positive charge on carbon will come exactly right it seems absolutely correct because chlorine gives up its electrons as well as carbon style attracts electrons will try to do it but this deejay is only electronic movement this is only The movement of sigma electrons is like this it's not that the electrons just went there The electron cloud is shifting Just because of electronegativity difference between carbon and chlorine which the electron cloud is on the chlorine side have to lean a little more because The negativity of chlorine and more so its does not mean electronic movement happened towards chlorine and both chlorine Electron Lake ran away, in such a situation there are many It will break, it is just made to be closed The movement of the electronic cloud towards him he can see the electronic density You are moving towards me, the difference is clear If so, then the negative charge on chlorine is There is a positive charge on carbon If it happens, then it is clear that these people these are the shad electrons from this carbon will be attracted and if this is from this carbon If they are attracted then their movement will also will be towards the carbon due to which this Carbon will also get a positive charge and Similarly, the carbon dioxide which is present in this carbon is the lions are the electrons they give 10 because of which it will be attracted to this carbon Because positive charge will come, that means if someone Tell me whose positive charge is on this carbon If it comes because of this then it is an indirect positive charge partial positive charge is chlorine that is because of chlorine in front An effect on carbon is inducing a positive charge on the carbon having This chlorine is creating the feeling of The induce defect on these carbons is which is called the inductive effect All these carbons can be said in reverse also A parcel is also made on top of chlorine by combining Debt mens are creating negative charge These people also have an effect on chlorine Indus means food, this is a due to electron negativity difference that's reducing the effect here which electronic movements that electrons Represents only the shifting of clouds just doing sigma electrons is representing the shifting and this Just because of electronegativity difference From here itself you can see that is of food This means that if you look at it carefully, All the carbons combine to form a single molecule on the chlorine side donating electrons to it or the electron cloud on the chlorine side Shifting to negative difference So that means one thing is clear, chlorine is The front shed is moving which tries to attract the electrons This is the minus eye effect of chlorine and the front carbon which blowing electrons towards chlorine This will be called a plus I effect i.e. blowing off the electrons this plus effect and sucking or pulling electrons date this mines eye effect is clear i.e. electronic and this is not what I'm doing It is happening like this, the molecule is bigger It was simple that I have provided the profile You should understand for yourself what is happening to us I know this is affecting me only to observe and study molecular properties Judging someone means eating this, this is what I mean I completely agree with the fact that Chlorine removed carbon from my food Did not attract chlorine already too much If the element is electronegative then it is carbon to attract electrons from the lion He will do it, that means I will only do this It was to be observed here that this effect could be reduced As far as the series is concerned, I have We have to take care of such groups which are plus do effect shows and groups that electrons reduce the amount of data in it mines eye effect show their series I have made this series, we will remember it Falling i.e. nr3+ or nf3+ is very strong -There are people who show eye effect As you progress you will see These groups that have been formed will give you mines I effect and these groups that have been created plus i am clear in mine i effect and Because of these plus effects, molecular There could be a big impact on properties such as Acidic nature Basic nature of carbocatenes Stability of Carbyne The stability of radicals has an effect on all these i.e. if I am inductive If I talk about effects then inductive effect molecular properties or intermediates How is the stability of this governed? It is something like this, if it is acidic in nature If someone is putting up a group then it is mine eye effect They increase the acidic nature of the molecule and if someone applies a plus effect If the group is involved then in this case molecular of molecules or it is called acidic of acids He will decree nature; I am also an example I am lying similarly if you are of basic nature If we talk, then just reverse it will be molecular the basic nature of will be good if there is any There is a group that is trying to blow electrons reduces because the electron that will be blown away He understands its basic nature as a molecule. it will increase the basic nature because it The molecule can easily transfer the electron to H+ can donate that molecule easily from h+ can be called near him i.e. Basic nature will change if you plus i The effect is similar if you have mine eye If you apply the effect then your basic nature degrees It will improve the stability of carbocations The question is Kar Plus I Effect Carbo Ke Timing will increase the stability of and brother C Effect on the stability of carbo ketenes This will reduce the downside for carbines free radicals will just like If Carborketayan is considered then Although the inductive effect of free radicals plays a major role in the stability of but still if I could see you every If it gets fanned from the other side then in such a case it is inductive The effect gave me answer to radicals You have to give in stability and plus The effect that will occur will be that of carbocations also increases stability and in this way The stability of free radicals is also If he tries to increase it then its I mean, these are molecular properties or Inductive Properties of Intermediates Now you can play an effect role better As far as the application is concerned, as I Now I am looking at generally molecular in the big property some when we check here inductive Finding answers to your questions by applying effects So generally the most important thing is I don't understand much about what I rule What reduces is charity, which I call I can say dump rule and distance numbers I can say the rule of power, you can do charity Can you remember me like I did today? i.e. the one who plays the biggest role that is the distance And then came the big numbers And then came the power of the big one I'm trying to tell you that when you molecular by using inductive effect If you own the properties then in such a case Distance plays the biggest role then Numbers and then power i.e. food This means that the effect of Zee Group is bigger Which group are you considering? I would have to check if it is on carbon if you keep increasing its distance Its effect will keep on decreasing i.e. the most Firstly the distance will decide whose The shorter the distance the more powerful the effect The distance of the G group will be more It will have less effect if the distance is If it happened with the group then there was inductive between both of us To check the effect you need to know their number You will read to check who has more number Whose numbers will have a better effect it is less, she will only fix it less even if the number is from If so, then consider their strength if their strength is equal to that of any other person The one who has more power is stronger The one who has less power will have less effect It will have a strong effect but it is powerful The rule of power is there between these two It will come after 'means eating' means this First of all, we will reduce our distance Although this rule has been made which Danpur is exactly said this rule generally in the series that you just wrote, Plus I and Mines I effect him in series Applicable to people from far and wide Gulab Singh has no move with his nf3 plus and one you added fluoride or chlorine or you took bromine now you are saying that If there is bromine nearby, then there is more It will have an effect, see, it is true that Inductive effect depends on distance but still this dump rule or donation Punya rule has been made, this is actually you Not for the very far-flung It was made, you understand what I am saying But you still say that Distance day number and give power like Let's take an example, mother, take this Let's talk about the example in this example I understand you are talking about acidic nature The whole world knows that they are acidic If we talk about nature then it is acidic nature Here's our man in the acidic nature show it will do because these are the groups that you Let's assume acidic group okay now If we have to decide which is the best among these How to decide which acid is good? will be made clear it is understandable sir fluorine Mines is a man who applies effects and many It is located at a short distance, here is fluorine There's fluorine here, and there's also fluorine is there i.e. power everywhere but I will not check the power first. First of all, I will decide a few things first I will decide the distance where this The distance of the group is the shortest and the It is going to have a strong effect, that is clear The closest thing to it all comes to mind I thought this man of ours was from CO group So which acid is considered the best? After that the A person should understand us clearly. I think the distance of fluorine is a little If C gets placed in B then B's turn should come If there is a little more flood then C's turn should come And the distance of fluorine from this cup is the maximum it is farther and the greater this distance the lesser will be the effect it will show i.e. The most fake man would be our Di in fact It is said that after three carbons, the group Whether you apply it or not, it doesn't matter Inductive effect depends on distance the more the distance increases The more its effect diminishes, that is First of all you should look at the numbers sorry first of all First look at the distance, then the numbers Look and after that you can survey the power now Just like as an example if I If I talk about this, then it can also be said that if this Chlorine is also attached to carbon, chlorine is also attached It has been applied, chlorine has also been applied and mother along with it Here you can take anything you want CO It felt good the same way with this carbon here you have fluorine applied here yes it seems there is one here too And now in this case generally if I use the power If you consider it then it becomes clear Fluorine mines II stronger than fluorine So if a child considers only power He will do the first one with the second one I felt it was a good blessing, that is, eating it means this If this one is P and this one is K then that one is the other asianet nature butter maa laga agar I only consider power because Fluorine mines gave strength to chlorine Mines came more than the power but deciding what is the factor, all the power will come later Firstly the distance will be decided and As far as the distance is concerned sir distance So it is common i.e. all these groups on G carbon I have started to distance myself from some of them and live All these groups are attached to carbon, their Distance is common then who will decide Then the number will come sir you are talking about power I will do it later and the number will win this time There are three numbers for chlorine here and Even if there is no flooring there but he has only one number infact Even if he has two, chlorine still wins That is, in such a case, the correct answer should be Pump dependent nature of the pump which can be used to make the butter want means to eat because this is The number is same here as well The rule will reduce the debt and that is our two virtues Rule date is given > N > P Under this rule you It can be easily determined that the acidic Tell me whose nature is better i.e. mashup I am having a very inductive effect These electrons do not have a strong effect does not represent a complete transfer of only causes movement of electron density represents and in such a case you can do something effects in some places you molecular Properties governed by inductive effects you can but if more than that If you were experiencing strong effects then you would They have to consider if and If I talk, the snake looks like this You can take the example of wala, see this your fluorine is at a distance from the carbon Your bromine is at a distance of from this carbon It seems you are at a distance from this carbon Chlorine has been applied and at a distance from it I have put my ID if you are also a student like this If we talk about it, I think this time, The value of distance is similar to that of numbers value is similar so that is deciding factor Bill B Power and Power is the best of them all Fluorine is the best offloading for us There should be a union of two, which means eating this Distance, then number, then power We should consider and discuss further Let's talk about basic nature, basic The rule of nature which has been made is a general rule The rule that has been made earlier is This is what you generally see in organic compounds If you talk about the basic nature then Nitrogen Compounds are Our Basic Nature There will be people doing the show if I'm organic If I talk about compounds, then in such a case if If you want to know the rule of basic nature then First of all you can check the availability of electrons You have to check the availability of have to look at the electrons which are being donated and the other which Criteria has been made for those electrons What is the tendency to donate to donate What is the tendency of your donation? Even if I get to know your tendencies, I will still be yours I can compare the basic nature of date with this Donation tendency means mainly these two Effects are two factors that affect any The basic nature of organic compounds Government does, however, another factor in which you both are good at Despite that the man is not showing his basic nature why is this happening because maybe you know the man you are going to give it an electron are going to give electrons standing out You want to call h+, that means these three People standing outside called h+ then the man who The more easily she calls h+ the more A good disguise will be made now in such a situation mother Look, I am a good man and I want to call you too I also want to donate the electron leg h+ in spite of that if yes it is not plus i told you i will not come also your basic nature can fall but date wise An unique cause of protonation you know that means there are two factors which Let us decide which basic nature is good for you or bad third which is unique cases in which h+ kaha hai brother you are such a good person that Like that is yours, I will not come to you If you pass then your basic nature is also bad It will be considered but how can this bill be unique which we will discuss later i.e. eating This means that if these criteria are met See, you can see the best base Sir if you look at this nitrogen carefully So we heard that this nitrogen is sp3 If you see, this is sp2 and this nitrogen is called If you see, this is SP and there is no doubt about it Sir if you talk about nitrogen then Nitrogen which is sp is obviously the better the more electro negative Today compare to nitrogen which is sp2 and it is more electronegative, which Nitrogen sp3 i.e. similar element Negative difference can happen because of Ask character means one thing is clear If your character improves then your Electro negativity should also be increased because of which molecular properties are required But it will have an effect similarly if I increase the carbon If I talk about this character of carbon By increasing the speed his electron met Grease should be applied i.e. carbon is also the most would be more electronic if that SP Yes in the form, compare them with each other Although, if we look at nitrogen The electron density of carbon is higher than that of But still if we look at it, then the carbon which has sp character is atlist nitrogen having better basic nature than sp3 That is, what does it mean to eat if these If we want to compare them all then nitrogen The sp character of will be from sp2 will be more electronegative then SP of carbon should come then nitrogen ka sp3 so on so on sword means big Electron negativity is a simple principle You will try to keep the electrons in place if you look carefully here The highest electronegativ It will be of nitrogen, what will he say, I will do that There is a man standing outside who doesn't care who was to donate the electrons to h+ h+ this will be there brother don't expect anything from me so I want to give very little because I have the highest electronegativities I will not keep it so which country is the worst C will be considered and as far as the best If we talk about base then nitrogen which is sp3 Whoever has the least activities is the most Easily donate electrons will try because of which it is the best Now you have to keep the basic nature but how to do this If I see this I will donate Its tendency is not very good, it is something If you look upset, it means this If I talk about the best bass then Our A will be the best base even after that after that there will be C because basic These are the two rules to decide strength Availability is the common deciding factor There is a donation tendency and there is a donation tendency Because of electronegativities, Nitrogen which is SP should be kept the lowest so the worst thing is to be clear and talk Let's move on to the next point There are even stronger effects than this There will be even stronger effects than this which governs molecular properties and that is our resonance effect Resonance effect is an effect which governs the molecular properties and You play a big role in molecules Intermediate of acidic nature Basic nature comparing the stability of etc In resonance it is said that any one Molecules are electronic by themselves If we look at the distribution, it Any electronic distribution The molecule should be exactly there Sometimes it is not necessary to say it, i.e. about eating It means that if mother takes this from you I say electronic movement this time you just the shifting of the electron cloud not talking this time you owed Talking about electronic movement that is, if you have electronic movement Electron density on different atoms Sometimes it is flooding, sometimes it is flooding, sometimes it is flooding Sometimes there was a flood, sometimes the ghat, today the electron is my head But if we go further, the electron density on me will increase After asking my head the flood got transferred to your head if you go away then your electron density The flood has occurred so give me the electronic movement Electron Density of Individual Items But keep on increasing and decreasing in this non today resonance But whose movement is it only in this It has only electronic movement Movement of atoms or nuclei is prohibited That means one thing is clear, if your atom If it shakes then you don't call it resonance This definition of resonance can end the matter The race is the one in which I do not come Electronic Movement Ho Diu Tu Pi orbital p orbital overlapping these Different due to electronic movement Electron Density Ghats Flooded on Atoms There will be a place which you will name as resonance That means eating means suppose if I am a If I take a simple example of benzene then I get this I understand that electronic movement If you look carefully then this thing which you drink electrons are these pi electrons The movement looks very easy, this P electrons can move very easily and that is why it has a new Form can become a new Lewis structure It can be made to look something like this show the power i.e in this how if you If we look carefully, then in benzene, P If the distribution of electrons is You say that one and you are on carbon number one If you stop drinking then what kind of things will you say? You do one and you drink on number, haven't you stopped? This means that any one of these Single Structure Electronic Not mentioning distribution clearly Could it mean that it is like this or it is like this because The actual situation of Ben Jin is something like this The real situation of benzene is such that These six p electrons are on these six carbons you are roaming around, understand that means this is Resonance hybrid this is the true structure which you call resonance hybrid Are what are you doing right brother electronic movement is happening and electronic This is because of the movement and what is the reason for this movement Sir it is happening from p orbitals is p If the orbitals are parallel, then they will be If the side vices overlap then sometimes your will overlap with it ever overlap with it I will do it sometime, I will overlap with it sir This overlapping will continue between the six carbons The electrons cry six times in possibile but for that sir p orbitals It is important that you are almost parallel to each other Let's say this p orbital is p By overlapping the side vice with the orbital P If you close it, sir, it will be a crime because this p orbital is p orbital with or this one p orbital sp with the orbital or this one p orbital this Side wise overlap with p orbital could sir other vice if this side vice If there is no overlapping then P will not be closed Because of which the electronic movement band Let this thing be understood, that is, if I Talk of building resonating structures If I were to do this, then the big ones of resonating structures I have said a very simple thing that If you look carefully one thing is clear All the resonating structures should be like this which should be a bonafide Louis structures There should be bonafide Louis structure i.e. He seems to be following Louis' concept No, you made all 50 blocks from carbon Just by looking at it I see it is absolutely wrong What Lewis structure did you try to create? If you try to make anything This is absolutely not possible sir because Five bonds of carbon are being formed, that is Also in the resonating structure you can see the carbon atoms in the can't make five closes because of the rules You can get rid of it only by following those rules can create resonating structures The second rule that has been made is this Designed with electronic movement can be seen but atomic or Nucleus movement cannot be seen For example, here Sir It looks like this is a positive charge These positive charges are called pi electrons. it is attracting you there is a reason for it sir Whether we consider it like this or p orbital overlapping Talk about p orbital overlapping absolutely Sir It is feasible sir, it is absolutely possible that this electrons these plasmas are Make it closed together i.e. possibility here Absolutely fine if that happens then sir a new A resonating structure will be visible in which Its positive charge will go there But P will go in between these two This is also possible, but if someone says that If this is its resonating structure then its Another resonating structure may occur when Take a hydrogen bomb from here and go here and here plus a goes this way this is wrong why because sir you were with me in this case You can see that you have a hydrogen movement is shown and if the hydrogen atom If you see the movement then it is absolutely not possible because resonating Structures or Resonating Structures There is one thing different in me, there is power and that electronic distribution but atomic The distribution of the nucleus is different It is absolutely possible that the distribution is different No, this rule has been made that if you are mine Creating Your Resonating Structure That is, I share my resonating structure with you. I am making it so as many resonating structures will form in all those atoms where only that movement will be visible of electrons due to which The electronic density never decreases on my head Sometimes it will be less on your head and sometimes on my head But it will be less sometimes, it will be less on your head but that electronic density above anyone else less because atomic movement is taking place yes this is not possible it is clear the third if Talk it out So the third thing is very clear, the whole world Do you know sir there is a condition of pinolity in this Who believes you have the condition of clarity? So it is very important if you are If we talk about sp2 then all the carbons of benzene are sp2 The world knows that sp2 are hybrids If we talk about hybrid then sp2 hybrid There would be a trigonal planar structure sir if you A quick look at the orbital diagram of benzene If we do then the orbital diagram of benzene will be This is what this orbital looks like Diagram of benzene all the carbons are sp2 if I talk about all the carbon All the carbon is my SP you are as far as The question of sigma bonding is very clear Sir Sigma band this one will be made of hydrogen all these sigma bonds will form together can be formed with hydrogen which is There is no doubt that I have seen all these sigmas with the closed hydrogen and all these sigma the bonds formed between carbon and carbon I showed the officer that he hasn't stopped drinking and he is a big man This is the case with pi bonding strength also shown Now if we talk about p orbital then you will see side wise overlapping which can also be created very easily if you Look carefully, there is a p orbital here. here's a p orbital here's a p orbital here is a p orbital here but there is a p orbital and here the p orbital is visible sir if you If we talk about resonance then this p orbital is The p orbitals are overlapping each other p orbital with this whole metal This p orbital is overlapping this overlapping with the entire orbital Sir, even these overlapping changes are power The possibility is that sir this wallpapering is like this If not, should I go to sleep i.e. electronic Movement of Perpend and Parallel p Orbitals It can be seen because of this i.e. One thing is confirmed if atoms taking partner resonance in which joe gave All of them are covered by local selectors If they are in the plane then the p orbitals would be parallel if you took any one carbon If the electron is bent, then its p orbital is also will become crooked due to which the person next to it By sidewise overlap with the p orbital If you are understanding what I am saying then don't stop drinking This means one thing is confirmed, clarity will play a very important role and just because you get pi electrons Payal has to give movement to everyone is possible when you talk about parallel orbitals Let's talk about the next point, let's make it clear As far as you are concerned, you are an important point which while creating the regulating structure should see and date is from this number off This is what it means to eat unpaired electrons that mother, if I tell you that this man A resonating structure of should be possible So I said of course you can make it If you show electronic movements So electronic movements are designed in this way can it be shown is this even possible It is absolutely possible Sir Electronic You can show the movements like this You can also make it the other way around if you want. This is though from both ch2's double penetration ch2+ you are doing absolutely right sir Electronic movement by any means It can be shown that these p orbitals overlap and the story is just that, you can see it say it by saying double single double single or you can say this Name the overlapping p orbital. These p orbital overlapping is exactly like you You can show it however you want but The important thing is that sir is it like this Can this be made as well, is this also possible The electronic movement is the This electronic movement is restricted although the makers can make this also yes but it is restricted why because sir there are unpaired electrons here You saw it sir, it is unpaired here too The electron is unpaired here too electron is sir here number off unpaired electrons are flooded i.e. You have unpaired electrons with this guy or two near this resonating structure there are unpaid electrons while actually which I had a molecule that had a single unpaid inside it it did not have any unpaired electron there are electrons and this rule has been made of resonance that you have initially Unpaid electors were illiterate even later electrons in every resonating structure due to the number of unpaired electrons i.e. this resonating structure is needed This should not be considered at all Considered absolutely wrong resonating structure yes both of them are possibilities They are similar to energy resonating structures are possible but this is the government There's something wrong here I don't understand because there are two unpaired electrons while it has only its if it does not have any of those electrons then also unpaired in resonating structure Electronic numbers do not flood or drain If you understand these clearly then you can While creating the regulating structure I had to keep these You may also need to take care of the button, it is clear Let's talk about the next point if you We talk about stability differently In Stability of Resonating Structures So however, some three-four rules were made in it They have gone but still the scientists say the same thing that generally we perceive things with our intuition Let us go, a voice has come from within us bro i like this more There will be a more stable resonating structure Although there is no priority order Yet four or five rules have been shown, i.e. Eating means that if I am the first one If I talk about the rule then date is complete Octant Octant Complete If yours is that the resonating structure in which each item The octant of is the most complete can be considered as a stable resonating structure Let's take an example like this Yes, I have asked this question before If you look carefully at this how Carbon update is not complete in this case The update to Carbon is not complete but it how carbon also has a complete octave and If the octant of oxygen is also complete then in such a case sir Even if oxygen has a positive charge yes but the second one is more stable than this First because in this every person gets updated It is complete, that means this is the most important thing comes under the category of rule in which it is said It is said that octant completion is achieved if any A look at each item in the regenerative structure when that resonating structure comes, it Largest among resonance hybrids is considered a contributor because he The most involved thing about the next point Now let's move on to a more covalent bond or Compare both the previous rules can be considered similar by doing the more Covalent bonds will resonate it The more stable it is in structure region is also closed formations energy release due to which it gets resonating Decreasing the structure's own energy It will go, that is, if I see this, then it's okay Sir you are in this Valent bond is extra meaning of eating So there are two pi bonds here, there is only one P is closed here also only one P is closed Sir, only second and third are visible So there is Shimla but the earlier one is more stable I guess why because inside the first one The number of covalent bands is more, that is The best must be our one one is the best and second and third they look the same to me because they so it is similarly clear I am able to understand that the meaning of eating is this Best resonating structure ever he is first because he has covalent bond if it is too much as per the next rule If you do this then the next rule is also made that if you talk about a neutral structure If you do this then it is considered more stable That is, if I talk about the structure first So this neutral if you are one of this If you create a resonating structure then it will be charged That is, eating means this, although it is not Octant says the update is not complete Completion etc. are all the rules but ultimately What is visible is that a neutral There is a charge, the tax separation will increase if Opposite charges will be kept away from each other So Sir, their energy will increase the more they The closer you are the more stable it will be As many opposite charges and similar charges as one They will be kept away from others and that much more stable The system will be considered to have similar charge which is passed I'll give you repulsion will be converted into neutral If the system has a resonating structure If we talk about neutral system then it is more important This system will be considered stable as compared to other systems And if we talk about one more thing then this is negative There is an important rule for this If in a resonating structure the electro The negative charge on the negative wind is a then it would still be considered better but if positive on electronegative element Negative on charge or electropositive If the charge is A then it is not a good situation Money will be given even though he is a contributor But he is not such a strong contributor will be as much as the other one would be considered i.e. If I take this resonating structure and this If I compare the resonating structure In this case, the carbon has a negative charge And in this case, the negative oxygen is Oxygen is more electronegative element so it has negative charge Still, carbon emissions will be tolerated above the one which is electropositive Negative charge will not be tolerated So there is no doubt about it either is a better contributor than the first one and Resonance hybrid can be considered as It is clear that there is another unique feature like this A can date is a resonating structure all the benzene you see in the The more benzene you see, the more Aroma City is considered more stable It will be like if I talk about naphthalene So how can naphthalene have a resonating effect And the resonating structure can be said to be and this pressure has a resonating Some suppose the structure can be made like this Both of these can be resonating structures The naphthalene men can go but their Despite this, this one is butterier than the previous one. would be considered because it contains two benzene systems are visible to me while its Only one benzene system is visible inside that is, and the compounds which have more benzenes or resonating structures in which The more benzoate structures you will see, the more as many contributors or more Considered as a stable resonating structure That's clear, let's talk about something else As far as you are concerned about the third effect Third, effective communication, however, you In the big resonance if I say one more thing Add where I can see resonance If he gives it then there are important conditions for it It was made according to me, if I look at it If we talk about the conditions of resonance then Let us also look at those conditions once If we talk about conditions then the conditions If I take a general step now Positive charge on alternate atom of double bond having double closure on alternate atom Presence of negative charge doubles the charge Another double close or triple on Alternate Atom Being closed means being P closed double closed of a free radical on the alternate atom of These are the situations and double the risk A negative sorry lone leg on the alternate atom There are five specific conditions for this to happen which is important for resonance Apart from caste there is something unique too There are conditions which we should pay attention to: and specifically I note separately I have been six There is an atom like this next to carbocations. Pay loan or carbs are cut for free There should be an atom next to the radical which is If you are on a lone leg, this is also a unique situation you of resonance which is related to this in which it is said that if on any one atom be on loan or have negative charge and its There is such an atom next to G on the spring P orbital or d orbital spring p and d If you axis the orbitals then this also and An important situation of resonance now money Ja Shakti means an item which has negative effect on the body whether it is on charge or on loan, there is a There is an element which has the same orbital or you are your orbitals so these electrons Dell may be offline in those spring orbitals There are other molecular properties like these impact on properties and address i.e. if I If I talk about specific situations then this is something There are specific situations where you I can see the resonance if I You need to build some resonating structures I try to do it in a very systematic way If I first talk about such a resonance which does not contain benzene or any aromatic One such item installed by the system is available on loan at Rs. Or is there a negative charge system The negative charge circulates inside the ring that is, this system you circulate this system circulates Negative Charge On Ortho And The meaning of eating is like if you take a mother I am a situation late in which there is an element I am late if there is some such situation this is phenoxide we understand Negative charge on the first atom adjacent to the ring then such a system is called a negatively charged ring What will be the way it will circulate inside Negative charge will circulate negatively Charge in and you understand the same story p orbital overlapping, that is, these ones the electrons will go here which It will become a resonating structure What the resonating structure will look like Its negative charge in the resonating structure Electronic movement will be charged here The electron density is changing because Then this man will do this with this negative charge Negative charge is present here due to resonance will come which will be the mercury position then this negative charge then there will be electrons and a A new situation will be created in which negative charge It will happen here and the bond situation will be like this And finally this is another resonating structure will be converted into in which the condition of the bond It will be like this and this time this negative charge is here hoga means this is what eating means there will be structures that So this phenoxide ion is in the form of will create this and this phenoxide and which in negative charge is negative charge In which positions has he been seen? If you can see him If we observe carefully then that negative charge is one A is in the ortho position One is coming on this proposition And the same woman is holding this position, i.e. Whenever the negative charge circulates, it Will circulate only in ortho or par positions Similarly, if there is any such Consider the situation in which you are doing this that a man like this was found with benzene before which the p band on the atom like support a And if this P is closed on G then it is connected to benzene If P is closed on the first item then such a system the positive charge will circulate Transpositive tax will circulate soon ortho and para i.e. ortho and para position You can see positive circulating A very simple example of which will come can go and date this suppose ch2 with appear the conversion of carbon into carbon and oxygen negative is less than oxygen then The electronic movement will be p orbital The overlapping will look something like this: The resonating structure which will be built first On this carbon in the resonating structure A positive charge will come and this oxygen negative and all situations will be like this In the next resonating structure electrons towards the positive charge You will be attracted to Pi orbital Overlapping this is your next resonating The structure will be formed here plus will come and here A Double closed CO mines will be If we talk about resonating structures in the next resonating structure here plus the situation will be somewhat similar and this Mines and Ha and Last Resonating It is structurally the same as it was before it will be converted, that means eating this that if I talk about resonating structures If I look at it in a way, then it is from the ring If the first atom is on loan or positive charge alone but this negative charge so Negative charge inside the system ring was circulating on orthoped opposition And a man who was first introduced to rings P is off on the item, such system is positive The general was talking about circulating the charge positive charge was circulating Reason for resonance on position on ortho and you molecular properties or intermediates The stability of this is to be seen in detail It is available, you can understand it as if by taking an example Let's take it mother, let him tell me this In both of these Which is more stable or more acidic? let's take it I'll take this watch and this note if I get it If you want to compare acidic nature then just It is wrong to derive the answer through inductive reasoning because According to inductive method, our second one he is a man he would be considered a better acid You are standing close by, will you pull more? It will make it easier to remove but from the inductive Which is more dominating than resonance? This means resonance effect because There is more dominating effect hence the vote will decide which of these two is better So as far as the question is which is a good acid There is a very easy way to find out the answer In the big discussion about no.2, we talked about who was no.2 Saa Jaa bet Sir hit the ring first atom has a double lock n double lock o then A positive charge will circulate for sure Where will the front sight be applied on the orthopedic What is the situation behind and what is the situation in front If there is position and position then definitely here Due to which effect will the positive charge come It will come sir it will come due to resonance effect ok ok no2 which tax circulates yes sir positive charge circulates Where does he do it and who produces it, but who is he? C position means resonance no2 This government will not be affected by this position This method is very important, it is very easy there is no exception to this, it is very easy these questions can be answered without any Use your mind to join the group In the big electronics distribution Think you will get the answer automatically no.2 sir is placed in a position that has resonance Effect not visible on meta position If he gets it then what will he do sir? This is just will apply inductive effect and the inductive key Because of which chase will give heart plus sir here there is plus a look because of this Here just because of the inductive heart plus a Sir Electrons are getting bigger with the arrival of Plus It will be easy to pull and take out the ha In which form will it go, in the form of h+ i.e. It will be easy to remove h+ so if this drink and why should I take this then drink this butter acid give same because of resonance Effect i.e. no2 of those drawing nature because of this mines are effect or mines Effect due to its acidic nature is increasing but if you are inductive If the answer comes out then you can choose the second one Butter, today we believe it's first because the second one is nearby It will suck more because of which today's removal will become easier in the plus form while Actually the resonance effect says that The no.2 group that sucks the most is the one that But apply these mines and mines If the eye effect is clear then it means that my food This means that the resonance effect is also molecular. governs properties which are large They play an important role because they are the most This is the more dominating fact to consider It is done, let's talk about the next point So next there is another permanent effect which you see something going on inside the molecules You just have to observe and date this Hypertonicity effect is a big situation Hyper can you congestion is very simple In this situation, we say that a carbon which is sp2 is the carbon next to the sp2 carbon which is sp3, hydrogen or halogen If there is a meeting then this situation Your hyper congestion situation is a money issue i.e. adjacent to sp2 hybrid carbon The carbon which should be sp3 if it is placed on if it is hydrogen or hydrogen then it is hyper of conjugation or reverse hyperconjugation situation and keeps you in such a situation This is such a resonance that you must understand it very clearly is the form in which you can do so electronically There is movement but it has Sigma Pilot of Electrons with Trans resonance means before you He was discussing resonance Resonance of p electrons which involved electrons Here sigma electrons are involved inside resonance which has a very simple For example, if I take protein When I observe, this is in the propane carbon my sp you this sp2 carbon The hydrogen next to it is sp3 Can you see what will happen now sir, these people sigma electrons are pi electrons There may be valves in resonance with The method is the same sir now you can see the orbital diagram If you make it then sir resonance means overlapping How is p orbital overlapping happening? because it is normally parallel It is not exactly parallel if you pay attention if we look at it from this perspective then it is possible that these ones sigma electrons are in sp3 orbital I have that with these adjacent p orbitals The side vices can overlap, this means that What happened sir, you can see the resonance situation these are all our sigma electrons all of our alpha hydrogens and all of that People can get involved in hyperconviction yes, what is the method, it is a very easy method sir It seems so if I look carefully So what I understand is that The sigma between carbon and hydrogen those electrons are sigma electrons Remove the sigma electron from here. If we go from here now, then Sigma electrons have a signal To whom do all the electrons reach All the Sigma electrons will go we gave it to carbon i.e. carbon The hydrogen bond is then transferred to this carbon Negative charge was obtained i.e. all signals Aatmosis Carbon has no such Situation of off situation became resonance of which key and resonance if this is the situation What will happen? This will come in and this will take it out. It will go the same way if we talk about other situations Do this, turn off and remove all these electrons Come here, this will come in and this will take it out It will go similar if we talk from here These are all on Sigma Electronic Carbon It will come in and it will go out. The situation seems very clear that you If we browse the resonance which is a There is no closed resonance because carbon there is no closure between the hydrogen then also hydrogen stopped here hypothetical Even though the situation is hybrid, why is this approach Because sir if you moved the atom So this is not considered any form of resonance It can be used i.e. it is an electronic movement Sigma electron resonance is taking place I have to understand everything but if the atom cannot move then This hydrogen will be like this electron signal electrons went there came back, went there, came back doing this propane that you bought these three hyperconjugation of the three alpha hydrogens to give it it has three alpha hydrogen If we talk about total structures from proteins come together to form a structure will appear one two three and one that We have a hybrid protein, that's for sure This situation of hyper congestion is clear it indicates many things if you pay attention If you look at it from the perspective then it is in its application part Firstly the stability of alkenes is also a power is that is if you talk about Elkins So hyper in the stability of alkins Congestion plays a huge role as suppose I am taking an alkene which has this There are methyl groups all around In the same way, an alkene is obtained In which mother take alpha hydrogen reduced some and or else such a situation I am lying down with some alpha hydrogen in it If you reduce it further then mother, if I get these Compare the stability of the three alkenes If you want to do it then compare their stability Time I just need to pay attention to what While comparing their stability, I found what will happen in place of alpha hydrogen more this is alpha position this is double closed is the alternate alpha this is also alpha this also alpha near it if i see it tomorrow meet 9 alpha hydrogen see near it So it is not good to meet tomorrow, if you see near this I have a total of 12 Hyper Alpha Hydrogen look at this one so it has no i.e. its It has 12 vault fight holes It has 9 there are alpha hydrogens and if we look at this It has only six alpha hydrogen now In such a case, Sir Elkins is seen with If you talk about stability So the more hyper you have Conjugate hyperconjugations will involve The more alpha hydrogen is involved Your stability will be greater You should think of it like this, just before this what did we see that our structure Double closed that double closed immediately in hyperconjugation As soon as one gets involved the double becomes single It becomes what you are looking for i.e. double closed If you become single, the more hypercon the more double closed the more single will be created and The more it becomes double closed, the more It will be considered more stable because it cannot be easily hydrogenated would mean eating this means if you If you look carefully, this double closed is the most How many times will you become single sir or 12 times It will become single because it is in all hypercons All these people will be hyper involved This is because of involvement in the concussion all closed our double closed again and again what he will become single this means young sir is the most Which honey should I drink that is more stable alkene? because it has the least hydrogen if it is too much then who wants honey and her what honey is needed after that and why because by increasing the alpha hydrogens Hyperconjugation increases, then hypercone increases The stability of the alkene will also increase i.e. A big role in Elkins' stability There is hyper conjugation, that is, if alpha If hypercongestion is increasing then Stability is also increasing It also increases the stability of the alkene let's be absolutely clear okay It may also play a role in stability How do you see if I'm on a carbo When I talk about time then this Caborketayan If you look carefully you can take it Is this our hyper congestion situation? I am satisfying myself, I am doing it for sure because this is the carbon next to it is sp2 This is sp3 yes but there is hydrogen so this sigma electrons which you alpha hydrogens can say these alpha Hydrogens May Be Involved in hyperconjugation i.e. this sigma Electron flood or resonance is involved which you can call hypercongestion You will tell the situation and a snake will appear It has a hyper conjugable structure which is It can be made such that it is Why is your stability increasing now? This way its three hyper concedes can be shown Can you understand what the three alphas are saying Why hydrogen can be involved Stability is increasing as G carbon But there was a shortage of electrons, so you called it carbon made him happy by giving electrons, what is this Inductive Only air hits the electrons from it Complete transfers are not possible with just one I have got the feeling, it is feeling good other wise effect and resonance effect which are It is a complete transfer sir that is a different matter level sir that is complete for carbo canteens stabilizes g on carbon in a way both of you were posted on carbon on carbon There was a positive charge at time t there were too few electrons The density was low, you gave it electrons Have you satisfied its octave? I have completed it means this sir These are the effects which you call resonance effects or it is called hyperconjugation effect There is more dominating effect and these effects more governed by molecular properties Today you are compared to inductive means if As I see it, this is because of Hypercon the positive charge on carbon is being lost similarly three sigma electrons may be involved due to which carbs The more the time stability of Carbo canteen will be more hyperginization the more stable it will be considered and the because of which it is called 3 degree carbo Cats are more of a 3° carbohydrate It is stable compared to the degree region Hypercon if you are talking about cutting 2° carbs If you do it then take a little time for 2° carbs will be bad and at the time of primary carbo Even worse men will go. there's nine alpha hydrogens here's 6 there's alpha hydrogens and there's only three Alpha Hydrogen You have the dominating effect of carbocations When calculating stability, however, I don't deny the role of inductive but Dominance is in fact hypercolony That means if my mother tells me that these two Which is the most stable carbohydrotest? So the child who is less intelligent is in a hurry I can write the answer wrong this carbo The cuts and these carborketions are clearly visible If a man is only inductive If one wants to find out the answer then he can find the answer Obviously the second one will be called butter because inductive power of ch2 ch3 is more than but actually it has 9 alpha hydrogens and it only has 3 2 5 2 7 alpha hydrogens so alpha Addition of hydrogens leads to alpha hydrogen will increase due to which carbs The stability of cations will also increase Why because hyperconjugation increases we will do this so cut this carob give this butter this carbo time because inductive then He just gives the feeling, satisfies it by donating electrons So the hyper convolution resonance effect is different Provides level stability carbo cations or molecular Stabilizers for properties at different levels let's do it, let's go right, next point If we talk about the radicals of closed length where till now the question is about the closed length also as I have just I told you that they also go to closed length There is no doubt that if I consume protein If I talk about its hyper congestion then Let's consider its hyper conjugable structure In You thought Zee Band was single I am actually becoming a double I am making a structure for the bandh He thought I was actually single Are you becoming single and are you understanding this? That means the more hypercons there will be double closed The more single he will become, i.e. a peacock Hyperconjugation of Peacock Bill B.D. Closed Length Off double off means double off as much will become single and the closed length of the double bond inside ethene in which you can take a closed length You are doing B and cutting a closed length So, if you are of A then the one who is A she will be considered bigger than b, why because you are talking about closed length Because there is hyper conjugation inside propane Three alphas inside the Involve Propane There are hydrogens due to which these double bonds are closed will become single thrice due to which he will become big it will be considered as comparison of ch2 ch2 now taking the flood i.e. the closed length of the double bond also Hyper convocation governs and so on Acidic and basic nature also gets this information Now it is a great asana if I meditate If I look at it from the outside, then the acidic nature also The hyperconjugation effect can help you Look, let's take this ch3 and here you have your mother ch2 ch3 taken now the child who is less intelligent he will look at it in an inductive way and he The plus effect of CH2 CH3 will remain ch3 is more than the plus i which Because the second person will have bad acid today When actually you were compared to the previous man The first man is worse than the second one What is the region, sir, you are hyper content Look sir this was sp2 hybrid carbon Look, this is sp3, ji but alpha Hydrogen is definitely our hyper The condensation effect will show when CH3 is removed from the ring If group or alkyl group is present then hyper The situation of congestion is clearly visible It's just like what we're talking about right now It happened sir this will be circulated as negative with electrons on the sigma electrons Resonance will circulate negative charge In which positions will negative tax be imposed It is circulating on and so on and position on Which tax will circulate negatively with Where will Orthopera do Orthopera But he is in the position in front of CH3 There will definitely be a negative charge here. it will be difficult to remove it whereas here also There is hyperaggression effect but here only There are two hypercation effects and there are three alpha hydrogen is so diu you this three alpha hydrogen effect this d hyperconjugation effect obsess three is butter give d hypercon effect of this ch2 ch3 because it is only you who can part i.e. hyper conjugation effect which is of ch3 that is butter plus ha effect of ch2 ch3 because it has two alpha hydrogens it has two alpha hydrogens and It has three alpha hydrogens to make sense here's the thing i.e. if I double close if my The alkyl group is in a position where where he can do a hyper conifer show That is, we are talking about the carbon next to sp2. If you are in such a situation then high caution Effect CS3 Butter will be compared today it is cs2cs but there is no doubt that If I talk about plus IF then the plus If there is an effect then that of CH3 will be less plus I am affected by CH2CL3 but it is dominating Effect if hyperconjugation is involved If so, then it doesn't matter sir 80 will win ch2c3 will lose i.e. my food means these are some effects that governs molecular properties Aromaticity within Next Molecules Or anti-aromaticity is also seen which enhances the stability of molecules If I talk about Aroma City so aromatic compounds would be those compounds Gym, these three conditions will satisfy you But if we talk about it then it is very clear that The aromatic system would be such a system which will be First of all condition should be this honey compound Whatever it is, it will be my cycle, the other one will be his cyclic de localization will occur inside and The third one is that electrons are localized He is involved and satisfies Hawkins rules do that and yes according to the rules it means 4n + 2y electron system, whichever electrons are involved that foreign plus you Follow the rule in which the value of n Zero one you three whatever it is power like Let us take an example: is this man aromatic? yes this man is aromatic because These three rules are satisfied in this man how are you sir this is cyclic yes How to know if it is cyclic, it will be visible There is no chemistry in this, we see it it is cyclic so this is cyclic so this is cyclic The number of electrons inside it cyclic hearts are involved should there be cyclic deluxation here yes it is yes sir all are p orbital is perpendicularly parallel if all p If the orbital is parallel then these are six of six P Orbitals will be involved i.e. cyclic D Localization seems to be a hope and How many total electrons are getting involved yes sir tomorrow we will get 6 p electrons Involvement is cyclic D looks like and If there is involvement of electrons then Here even tomorrow the rule will satisfy you if you put one in place of n i.e. Huckle rule also It will satisfy if we put n1 then it will be 4 * 1 + 2 dates give it 6 electrons i.e. my account This means a compound that there is a cyclic inside which There should be delocalization i.e. electronic movement It should be cyclical in such a situation if that famine If the rule satisfies then it is called aromatic the system will be called and otherwise if someone If the molecule is cyclic then there is cyclic inside it there may be delocalization but still it is aromatic no why because there is four instead of tomorrow and the five electron system is following This means eating something like this system in which you first set the condition being satisfied in which the second condition I am also getting satisfied but the third Which condition is not being satisfied that is the Huckle rule so in that case, that is if she Akluj is not satisfying so in that case it is ours neuro-traumatic system would be considered So you can see here the p orbital is perpendicular and parallel then here The total involvement of electrons is that our four umpire electron system can be considered but four and plus two system It cannot be accepted if such a system is ours Egg aromatic system will be considered a diamond character will maintain your aromatic system and which is a traumatic system with a primary character will keep more unstable situation It will be non-traumatic, i.e. if the stability If we talk about it then the neuro-mechanical system is less give stable non aromatic system it is li Stable aromatic system i.e. most Our aromatic system is more stable then there will be non aromatic systems and then Which will be the non-aromatic non-aromatic ones? People who suffer from any of the above two conditions We will make the condition violet i.e. above From now on, if any situation creates trouble for us, If it goes then it will become non aromatic Like yes sir there is ethanol how does it feel sir now a romantic Aroma has no meaning in nature cyclic dialyzation should be cyclic I want honey and then I should be satisfied tomorrow Sir, ethanol is not cyclic it cannot be aromatic it should be non aromatic or if the compound which has two conditions After satisfying the third condition, if That foreign plus if you satisfy me Aromatic if it satisfies 4.5 introvert and if he/she is one of the above two If she gets pregnant then she should use non aromatic It goes into the category Clear Now let's talk about the next point Talk to the elders quickly in case of special cases Let's take this date and ship it The effect is such that the steering will be refected Initiation of Resonance AAP Second Ship Study The invitation of protonation of the first point If we talk about strike inhibition of Resonance says that sometimes you It can be seen that people's hair Because of the steering factor a man This is not getting involved in the resonance It is absolutely possible, that is, eating means this What happened is if I look carefully then this ch3 which you can consider like a tree can ch3sp3 hybrid be there sir like this Although a tree is planted like this The molecule is too small to have its own The molecular weight is less than that of oxygen it will happen but inspite of that you sir this sp3 It is a hybrid sir, it is a tree like this You have also planted another tree next to it Sir this sp3 hybrid trees fall due to wind These trees rotate sir, when they rotate then this way they bump into shops and you If you look carefully then disinu tu is they When you hit the shop and o2 Anu you say this to hell with you Our Nepal is among us. Crowding to mix this stereo I will go around in circles, that is, around eating This means that no.2 changed his plane. because of which no2 which is the first The one in resonance was the one whose p orbital is could overlap with the whole of its rotation Why did you turn around, what was the benefit sir Telefill has reduced due to which now the new no.2 will not be involved in group resonance and no2 if not involved in resonance So this is due to the stability of phenoxide ion. will it be considered a bad thing for you or if your If we talk about method then we can find no resonance It is just remaining which tax will circulate sir Dil Plus only due to inductive effect If you give this note then it will create resonance even today sir positive charge circulates first Which effect will give a positive charge on this position? from sir resonance effect from sir ha ka It would be considered quite easy to remove, just a second The man will be considered a good acid first person Man means all the hyper hyper effects of ch3 inductive inductive despite being fitted inspite of this science is no.2 because its Resonance effect dominates no2 G means the resonance effect which has higher It is dominating sir in such a case no.2 comes one was placed in such a position where the resonance I could have shown the effect but you were Cystic Repulsion He changed his plane due to which its resonance Involvement is now banned, now what is this just Now it is just inductive, showing effect The effect is showing and inductive no2's It has to be sucked which is slightly acidic in nature It was very big but sir here the note is Sir, he is also on the plane, there will be resonance today too And because of involvement in resonance sir Even today it is necessary to renouncing the signature the reason is that this man will increase the mines R effect is showing but this one The man is just showing his mine eye Because of this, A does not have much effect on the acidic nature there is so second compound if I Why should I take this and drink it? kee it more acidic drink no doubt you S I R Similary If I Have Same Effect If I talk about it then such a hip effect is a different It is an effect, what does he say, he also says it Look, tell me this is the best among all these Which base do you like then I said in this There is nothing to think about sir, this is ch3 right now There was a talk about ch3 hyper conifer show yes which tax circulates negative Where does the orthopedist do this? Ortho position so sir for sure here is negative Because of this negative charge, there is a charge on the loan If you run away then it means the best base then it should be the first one, why sir this in the first and in R the hypercone is of ch3 Tara position negative absolutely correct but Sir, inductive ch3 will be less useful here, do you understand This thing seems less inductive than it is It will not be a good base as it is fast i.e. This is the best confirmation logic it should be then it should be R then why and most of all we should have gold There is no doubt that the logical answer is this I want the same because in this how to drink + yes effect is also happening along with it plus Eye effect is also going inside this R plus It is becoming very important as well as small plus i effect is giving you distance Only plus effect is happening inside this And it is not getting anything inside it i.e. This means eating science plus yes plus I believe this is the same basic nature no increase Do you have electronic repulsions? Because of which who is the logical best I want more methyl aniline while actually Ortho Methyl Allium is considered the worst among them all Base is considered i.e. actual this no the actual answer is the best one is r then why is it then it is s and the worst Our P will be considered Diu Tu Steering Inhibition of Protonation what is the reason behind this method Protonation is very clearly understood sir when If you put a 'ha' here then it will be called 'ha'. repulsion will flood with ch3 the protonation you did after that The energy of the protonated system is very high this will be nh2 sir with this nh2 you have done Now if you have planted a tree, If you try to protonate then you will understand Take this equilibrium backward will try to run away in the direction Because yes it feels electronic repulsions of this carbon of this hydrogen Flooded with trees, Diu Tu Dis Electronic Repulsion is the making of this cut This electronic thing is repulsion starts because of these repulsions This protonation is not considered feasible and This reaction moves backward i.e. Similar to this nitrogen is also seen but there's a lone leg on the gee right now when this catches a If he goes then he will be a little further away from will move closer to the trees due to which electronic n due to which the repulsion will start and the cuts made will be Stability will fall which means everything is good I had my hands on the loan, I wanted to run away wanted to be hyperconfident every day Because of Tha inductive Bhagat wants here want to run away but still who can't Sir, he wants to come, why is he refusing? because he thinks that if I am here If this happens then the cuts that will be made will be due to this repulsion because of this it will be unstable so this time this The basic nature of man will decrease i.e. This effect is called non-strict inhibition of protonation i.e. strike initiation of also because of protonation i.e. strict Factors that may cause the non-protonation Protonation due to studied factors Insibit hona is also non strict Initiation of protonation which is basic in nature that is, these were some effects that Known as the important effects of You go to the gym, there is another unique effect Considering a similar SIR effect, which can be seen inside Benoit acid can get Benoi's acid asked for which is generally ortho substituted benzoic acid that is if I here But if any group is formed then it is generally called of women who take substituted benzoic acid generally they are more basic sorry dear More acidic give benzoic acid and dewar other N Position isomers means this is what it means to eat that this man is irrespective of his nature Of D group means you are understanding the matter this irrespective irrespective one by one general Sir I am discussing Irrespective of D Nature of D group Position Isomers Position isomers and Benzoic acid what is going on inside So what I am understanding is that this electron density is pushing towards some well if somehow this electron Know the density outside or near something Acidic nature of the rock what's the problem with that yes of course That is correct and the way to stop it sir is a tree Put it, that is, put a group next to it Give me the sunlight which can make the matter worse Sir, this man will get upset as soon as he applies it shop molecules and it will be annoying He will cry and the resonance will come as he cries The band will be with the ring and will produce resonance As soon as the band was formed, this was the effect that became acidic Are you understanding that nature is being destroyed? The effect is reducing the acidic nature Acidic Nature And if this happens then shoot acidic nature The acidic nature suddenly increases why is it so because sir the effect which it has That effect was reducing the assuring nature How did the band happen? Sir, one side got banded. due to grouping in steering CO2 is responsible for its pallor Cloud Gives Resonance Band with Ring the electrons come up and the band starts moving due to which the dependent nature If I could increase this thing, it would be very easy, sir There is power visible as if a big straight Let me take an example sir, see this here ch3 is installed sir look here is a cm3 Look, it has been planted on both sides. Sir it was awesome in this situation sir it was very clear that because of planting of trees on both sides Because of planting trees, everything becomes stronger and effect will be seen due to which most Good acid is ours and so is the reason for the effect it will be third and you will pay this bill b the second and worst man ours and The first consideration will be about food Meaning it is very clear, no effect is considered If you are not doing the ortho position Talking about substitution at ortho position By doing this you can understand the acidic nature of benzoic acid Suddenly there is a flood, this effect is not today Effect is a very simple concept which Key Resonance which is General Organic are seen inside chemistry According to me, they should be revised properly once. Let's have a little more detailed discussion If done with practice then you can understand them If I can go then I will discuss only this much today. I want the next class in the next lecture again Let's move on to the next topic thank you thank you so match