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Understanding Reversible Reactions and Equilibrium

Apr 9, 2025

Free Science Lessons: Reversible Reactions and Equilibrium

Key Learning Objectives

  • Describe what is meant by a reversible reaction.
  • Understand the concept of equilibrium.
  • Describe energy changes in reversible reactions.

Reactions Overview

  • Irreversible Reaction Example:

    • Reaction: Magnesium + Oxygen → Magnesium Oxide
    • Characteristics: One-way arrow indicating the reaction only goes forward. Magnesium oxide cannot revert to magnesium and oxygen.
  • Reversible Reaction Example:

    • Reaction: Ammonium Chloride ⇌ Ammonia + Hydrogen Chloride
    • Characteristics: Double arrow indicating the reaction can proceed in both directions.
    • Changing Conditions:
      • Heating drives the forward reaction.
      • Cooling drives the reverse reaction.

Energy Changes in Reversible Reactions

  • Hydrated Copper Sulfate Example:

    • Reaction: Hydrated Copper Sulfate (blue) + Heat → Anhydrous Copper Sulfate (white) + Water
    • Forward Reaction:
      • Endothermic: Energy is absorbed when converting to anhydrous copper sulfate.
    • Reverse Reaction:
      • Exothermic: Energy is released when adding water back to anhydrous copper sulfate, making it hot.
  • Key Point:

    • If a reversible reaction is exothermic in one direction, it is endothermic in the opposite direction.
    • The same amount of energy is transferred in both directions.

Equilibrium

  • Definition: Equilibrium occurs when the forward and reverse reactions take place at the same rate in a sealed container.
    • No reactants or products escape from the container.
    • Important for understanding how reactions balance under certain conditions.

Exam Tips

  • Learn the copper sulfate reaction as it is frequently asked in exams.
  • Use the revision workbook for practice questions on reversible reactions.

These notes summarize the key concepts of reversible reactions, energy changes, and equilibrium as discussed in the lecture. They provide a foundation for further study and exam preparation on this topic.