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Understanding Ionic Compounds and Formulas (Part A)

Apr 11, 2025

Chapter 5: Molecules through Compound Learning Objectives

Overview

  • The chapter is divided into three parts:
    • Part A: Chemical Formulas and Ionic Compounds
    • Part B: Molecular Compounds
    • Part C: Acids and Formulas

Part A: Chemical Formulas and Ionic Compounds

Chemical Formulas

  • Express information about atoms in a compound.
  • Indicates elements present and the relative number of atoms.
  • Examples:
    • Water: 2 hydrogen atoms, 1 oxygen atom.
    • Hydrogen Peroxide: 2 hydrogen atoms, 2 oxygen atoms.

Types of Compounds

  • Pure Substances are divided into elements and compounds.
    • Elements: Cannot be chemically broken down (e.g., helium, oxygen).
    • Compounds: Composed of two or more elements (e.g., water, table salt).
  • Types of Elements:
    • Atomic: Single atom as the basic unit (e.g., helium).
    • Molecular: Two or more atoms bonded together (e.g., hydrogen gas).
  • Types of Compounds:
    • Molecular Compounds: Covalently linked nonmetals.
    • Ionic Compounds: Consist of a cation and an anion.

Ionic Compounds

  • Composed of positively charged (cation) and negatively charged (anion) ions.
    • Example: Sodium chloride (NaCl)
  • Properties:
    • Strong ionic bonds.
    • High melting and boiling points.
    • Solid at room temperature.
  • Ionic Formulas:
    • Consist of a positive and negative charge (overall neutral).
    • Balance charges to write the compound formula.
    • Example: Sodium (Na) and Chlorine (Cl) form NaCl.

Writing Ionic Compounds

  • Procedure:
    1. Write the metal (positive charge) first.
    2. Write the nonmetal (negative charge).
  • Examples:
    • Magnesium Chloride: MgCl₂
    • Calcium Bromide: CaBr₂

Naming Ionic Compounds

  • Binary Compounds: Two elements, name cation first, then anion with '-ide' ending.
    • Example: Sodium Chloride
  • Transition Elements: Indicate charge in the name.
    • Example: Iron (II) Chloride

Polyatomic Ions

  • Cations:
    • Ammonium (NH₄⁺) is the primary polyatomic cation.
  • Anions:
    • Common examples include nitrate (NO₃⁻), sulfate (SO₄²⁻), phosphate (PO₄³⁻).
  • Naming Polyatomic Compounds:
    • Example: Sodium Nitrate (NaNO₃)
    • Use parentheses for multiple polyatomic ions.

Oxyanions

  • -ate Anions: Common polyatomic ions with oxygen.
    • Examples: Nitrate, Sulfate
  • -ite Anions: Remove one oxygen from -ate anions.
    • Examples: Nitrite, Sulfite

Summary

  • In Part A, focused on ionic compounds: definition, examples, writing, and naming.
  • Discussed simple ionic compounds and polyatomic ions.
  • Emphasized the importance of memorizing common polyatomic ions and their charges.

Next, proceed to Part B for molecular or covalent compounds.