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Colorimeter and Benedict's Test

Sep 13, 2025

Overview

This lecture explains how to use a colorimeter with Benedict's test to more precisely determine glucose concentration in a solution.

Recap of Benedict's Test

  • Benedict's reagent is blue due to copper (II) ions (Cu²⁺).
  • Reducing sugars like glucose donate electrons, reducing Cu²⁺ to Cu¹⁺, forming a red precipitate.
  • The color change from blue to red indicates the presence and approximate amount of reducing sugar.
  • The Benedict's test is semi-quantitative; brick red means more glucose than green.

Principle of Colorimetry

  • After the reaction, the remaining solution is less blue because some Cu²⁺ ions have reacted.
  • The higher the glucose concentration, the less blue the solution remains.
  • Subtle changes in the blueness may be hard to detect by eye, so a colorimeter is used.
  • Before using a colorimeter, filter off the red precipitate to leave only the solution.

How a Colorimeter Works

  • A colorimeter shines light (usually red) through the filtered Benedict's solution.
  • Benedict's solution absorbs red light the most, as red is the complementary color to blue.
  • A red filter is used so mainly red light passes through the sample.
  • Less blue (more reacted glucose) means less red light is absorbed and more is transmitted.
  • The transmitted red light is detected by a photoelectric cell, indicating glucose concentration.

Key Terms & Definitions

  • Benedict's reagent — a chemical solution used to test for reducing sugars.
  • Reducing sugar — a sugar that can donate electrons, e.g., glucose.
  • Colorimeter — a device that measures the absorption of specific wavelengths of light by a solution.
  • Photoelectric cell — a sensor that detects the amount of transmitted light.
  • Complementary color — a color that is opposite to another on the color spectrum; red is complementary to blue.

Action Items / Next Steps

  • Watch the next video for the detailed procedure of using a colorimeter to measure glucose concentration.