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ICP-OES Spectrometer Overview

Aug 17, 2025

Overview

This lecture explains how ICP-OES spectrometers, such as the SPECTRO ARCOS, analyze the elemental composition of substances with high precision.

Purpose of ICP-OES Spectrometer

  • Used to analyze and determine the elemental composition of sample solutions.
  • Converts a sample solution into light and then quantifies the elements present using the light's properties.

Working Principle of ICP-OES

  • The sample solution is introduced into a peristaltic pump.
  • The sample passes into a nebulizer, transforming it into an aerosol.
  • In the spray chamber, larger droplets are removed, leaving fine droplets for analysis.
  • The fine aerosol enters an extremely hot plasma, causing atoms and ions to emit light at characteristic wavelengths.
  • Optical components capture and disperse this emitted light into individual spectral lines.

Measurement and Data Analysis

  • The intensity of emitted light at specific wavelengths correlates with the concentration of each element.
  • A sealed, high-resolution optical system records the dispersed light on a detector array.
  • Computer software translates recorded wavelengths and their intensities into precise elemental concentrations.

Applications and Suitability

  • ICP-OES spectrometers provide highly accurate and reliable elemental analysis.
  • Advanced models like the SPECTRO ARCOS are ideal for high-throughput laboratory settings due to their reliability and accuracy.

Key Terms & Definitions

  • ICP-OES (Inductively Coupled Plasma Optical Emission Spectrometry) — a technique for detecting and measuring elements using light emitted from a plasma.
  • Plasma — an extremely hot, ionized gas used to excite atoms so they emit light.
  • Nebulizer — a device that converts liquid samples into an aerosol for introduction to the plasma.
  • Spectral Line — a specific wavelength of light emitted by an element’s atoms or ions.
  • Detector Array — an electronic device that records the light emitted at different wavelengths.

Action Items / Next Steps

  • Review the working steps of ICP-OES for better understanding.
  • Familiarize yourself with key terms and process descriptions for future reference.