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Biological Macromolecules and Reactions

Sep 19, 2025

Overview

This lecture explains how biological macromolecules are synthesized and broken down, focusing on dehydration synthesis and hydrolysis reactions, and their regulation by enzymes.

Biological Macromolecules: Overview

  • Biological macromolecules are large, carbon-based molecules essential for life.
  • The four major classes are carbohydrates, lipids, proteins, and nucleic acids.
  • They are organic, usually containing carbon, hydrogen, oxygen, and sometimes nitrogen or other minor elements.
  • Macromolecules make up most of a cell's dry mass.

Dehydration Synthesis (Condensation)

  • Monomers are single subunits that bond together to form polymers.
  • Dehydration synthesis joins monomers by forming covalent bonds and releasing water.
  • In this reaction, a hydrogen atom from one monomer and a hydroxyl group from another combine to make water.
  • The process requires energy and produces larger polymers from smaller monomers.
  • A single monomer type like glucose can create various polymers (e.g., starch, glycogen, cellulose).

Hydrolysis

  • Hydrolysis breaks down polymers into monomers by adding water.
  • The reaction splits covalent bonds; one fragment gains a hydrogen atom and the other gains a hydroxyl group.
  • Hydrolysis is essentially the reverse of dehydration synthesis.
  • This process releases energy and is common during digestion.

Role of Enzymes

  • Dehydration and hydrolysis reactions are catalyzed by specific enzymes.
  • Each macromolecule class is broken down by its corresponding enzyme type.
  • Examples: amylase breaks down carbohydrates; proteases (like pepsin) break down proteins; lipases break down lipids.
  • Enzyme-catalyzed hydrolysis in digestion makes nutrients available for absorption and energy use.

Key Terms & Definitions

  • Macromolecule — a large molecule formed by the joining of smaller molecules, usually by a condensation (dehydration synthesis) reaction.
  • Monomer — a small molecule that can join with other similar molecules to form a polymer.
  • Polymer — a large molecule formed from many monomers joined together.
  • Dehydration Synthesis — a chemical reaction that builds larger molecules from smaller units by removing water.
  • Hydrolysis — a chemical reaction that breaks polymers into monomers by adding water.
  • Enzyme — a protein that speeds up (catalyzes) chemical reactions in living organisms.

Action Items / Next Steps

  • Review visual representations of dehydration synthesis and hydrolysis online.
  • Prepare for further study of each macromolecule type in upcoming sections.