Overview
This lecture covers temperature and energy units, explains specific heat, and demonstrates how calorimetry is used to calculate the caloric content of foods.
Temperature Units
- The U.S. customary unit for temperature is degrees Fahrenheit (°F).
- The metric unit for temperature is degrees Celsius (°C), also called centigrade.
- The SI (International System) unit for temperature is Kelvin (K).
- Freezing and boiling points of water: 32°F/212°F (Fahrenheit), 0°C/100°C (Celsius).
- One degree Celsius equals 1.8 degrees Fahrenheit.
- Kelvin is calculated as °C + 273; all Kelvin values are positive, starting at absolute zero (0 K = –273°C).
Energy and Calorie Definition
- Heat is a form of energy measured in calories.
- One calorie is the energy needed to raise the temperature of 1 gram of water by 1°C.
- Different substances require different amounts of energy to raise their temperature—this is called specific heat.
Specific Heat
- Specific heat is the amount of energy needed to raise the temperature of 1 gram of a substance by 1°C.
- Water’s specific heat is 1 cal/g°C; copper’s is 0.092 cal/g°C.
- Specific heat serves as a conversion factor between energy and temperature change.
Calculating Energy Using Specific Heat
- The energy (in calories) required to heat a substance:
heat = mass × specific heat × temperature change (ΔT).
- Example: Heating 1000 g of water from 20°C to 50°C requires 30,000 calories.
Calorimetry and Food Calories
- A calorimeter measures the energy content (calories) of food by burning it and heating water.
- The equation used: calories released = mass of water × specific heat × (final temp – initial temp).
- Food labels in the U.S. use "nutritional Calories" (capital C), where 1 Calorie = 1000 calories (1 kilocalorie).
- Example: Burning half a bagel heats 1000 g water from 22°C to 92°C, releasing 70,000 calories = 70 nutritional Calories = 70 kilocalories.
Food Energy Content
- 1 g carbohydrate = 4 kilocalories (nutritional Calories)
- 1 g protein = 4 kilocalories
- 1 g fat = 9 kilocalories
- Example: Whole milk (12 g carbs, 9 g fat, 9 g protein):
- Carbs: 12 Ă— 4 = 48 kcal
- Fat: 9 Ă— 9 = 81 kcal
- Protein: 9 Ă— 4 = 36 kcal
- Total = 165 kcal
Key Terms & Definitions
- Calorie (cal) — Energy to raise 1 g water by 1°C.
- Specific Heat — Energy required to raise 1 g of a substance by 1°C.
- Calorimeter — Device for measuring energy content of food by heat transfer.
- Nutritional Calorie (Cal) — 1,000 small calories (1 kcal); used on food labels.
- Kelvin (K) — SI unit for temperature; absolute zero is 0 K.
Action Items / Next Steps
- Practice calculating calories using specific heat equations.
- Review energy content conversion for carbohydrates, proteins, and fats.
- Complete any assigned calorimetry problems or readings.