CHM 103 Ch 2

Sep 15, 2024

Lecture Notes: Energy and Matter in Chemistry

Key Concepts

  • Chemistry: Study of matter, its properties, how they interact with energy.
  • Matter: Tangible materials with mass and space.
    • Composed of small particles called atoms.
    • Can form groups called molecules.
    • Matter categorized into pure substances and mixtures.

Matter Details

  • Atoms: Basic building blocks of matter, smallest unit in chemistry.
  • Subatomic Particles: Smaller components of atoms, discussed in particle physics.

Energy in Chemistry

  • Energy: Capacity to do work, exchanged in physical/chemical processes.
    • Physical/Chemical Changes: Involve energy exchanges.

Categories of Matter

  • Pure Substances: Identical repeating units.
    • Compounds: Molecules with more than one type of atom (e.g., water H2O).
    • Elements: Identical atoms (e.g., pure gold).
  • Mixtures: More than one substance mixed physically.
    • Homogeneous Mixtures: Uniform appearance (e.g., salt water).
    • Heterogeneous Mixtures: Visible different parts (e.g., sand in water).

Properties of Matter

  • Physical Properties: Observed without changing the material.
    • Examples: Color, melting point, density.
    • Physical Changes: Change in shape or state, not composition.
  • Chemical Properties: Observed during chemical changes.
    • Chemical Changes: Substances form new compounds (e.g., burning paper).

States of Matter

  • Solids: Fixed shape and volume.
  • Liquids: Fixed volume, variable shape.
  • Gases: Variable shape and volume.

Temperature and Energy

  • Temperature Measurement: Celsius and Kelvin scales in science.
    • Kelvin: Absolute scale, no negative numbers.
  • Energy Types:
    • Potential Energy: Stored energy (e.g., chemical bonds).
    • Kinetic Energy: Energy of motion.

Measurement of Energy

  • Joule: SI unit of energy.
  • Calorie: Energy unit, often used in food energy.
  • Conversions:
    • 1 Calorie (kcal) = 1000 calories.
    • 1 calorie = 4.184 joules.

Specific Heat Capacity

  • Specific Heat (c): Heat required to raise temperature of 1g of substance by 1°C.
    • Water: 4.184 J/g°C.
  • Heat Transfer: q = mcΔT.
    • q: heat energy (Joules or calories).
    • m: mass (grams).
    • ΔT: change in temperature (°C).

Heat and Temperature

  • Heat Transfer: Hot objects lose heat to colder objects.
    • Equal heat gained and lost in a system (calorimetry).

Heating and Cooling Curves

  • Graphs showing temperature vs. heat added/removed.
  • Heat of Fusion: Energy to melt a solid (334 J/g for water).
  • Heat of Vaporization: Energy to boil a liquid (2260 J/g for water).
  • Phase Changes: Flat regions on curves; no temperature change during phase changes.

Practice Problems

  • Conversions and Calculations: Practice using equations and concepts.
    • Example: Determine specific heat, phase change energy, and heat transfer calculations.

Summary

  • Matter is categorized and understood through its interactions with energy.
  • Various methods to measure and calculate energy changes in physical and chemical processes.