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Crude Oil and Fractional Distillation

Jun 12, 2025

Overview

This lecture explains what crude oil is, how it is formed, and describes the process of fractional distillation to separate its components.

Crude Oil: Formation and Source

  • Crude oil is a fossil fuel found deep underground, formed from dead plants and animals (mainly plankton) over millions of years.
  • It consists mostly of hydrocarbons, particularly alkanes (compounds containing only hydrogen and carbon).
  • Crude oil is non-renewable, meaning it will eventually run out if consumption continues at the current rate.

Fractional Distillation Process

  • Fractional distillation separates crude oil into different hydrocarbons based on their boiling points.
  • Crude oil is heated until most becomes a gas and then passed into a fractionating column.
  • The column is hottest at the bottom and cooler at the top.
  • Hydrocarbons condense back into a liquid when they reach a region cooler than their boiling point.

Fractions and Their Uses

  • Long-chain hydrocarbons (high boiling points) condense at the bottom, producing substances like bitumen and heavy fuel oil.
  • Shorter-chain hydrocarbons (lower boiling points) rise higher and condense higher up, producing diesel, petrol, and kerosene.
  • Very short-chain hydrocarbons (like propane and butane in LPG) may remain as gases.
  • Shorter-chain fractions are more flammable and make better fuels.
  • Longer-chain hydrocarbons are often used for other purposes or broken down further by cracking.

Petrochemicals and Their Applications

  • Petrochemicals are all substances obtained from crude oil fractions.
  • They are used as feedstock to make solvents, lubricants, polymers, and detergents.

Key Terms & Definitions

  • Crude Oil — Unprocessed oil extracted from the ground, mainly a mixture of hydrocarbons.
  • Hydrocarbons — Chemical compounds made exclusively of hydrogen and carbon.
  • Alkanes — Saturated hydrocarbons with only single bonds between carbon atoms.
  • Fractional Distillation — A process that separates substances in a mixture using differences in their boiling points.
  • Fractionating Column — The equipment used for separating vapors during fractional distillation.
  • Fractions — The different hydrocarbon groups collected at various levels in the fractional distillation column.
  • Petrochemicals — Chemicals derived from crude oil used as raw materials in industry.
  • Feedstock — Raw material supplied to a process for conversion into products.

Action Items / Next Steps

  • Review the process of cracking of hydrocarbons, which will be covered in the next lesson.