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Understanding Strong and Weak Acids and Bases

May 4, 2025

14.7: Strong and Weak Acids and Bases

Learning Objectives

  • Define strong and weak acids and bases.
  • Recognize an acid or a base as strong or weak.
  • Determine if a salt produces an acidic or a basic solution.

Strong and Weak Acids

  • Strong Acid: An acid that dissociates 100% into ions (e.g., HCl → H⁺ + Cl⁻).
  • Weak Acid: An acid that does not dissociate completely in solution (e.g., HC₂H₃O₂ ⇌ H⁺ + C₂H₃O₂⁻).
  • There are very few strong acids. If an acid is not listed as a strong acid, it is a weak acid, regardless of the percentage ionization.

Examples of Strong Acids

  • HCl (Hydrochloric acid)
  • HBr (Hydrobromic acid)
  • HI (Hydroiodic acid)
  • HNO₃ (Nitric acid)
  • H₂SO₄ (Sulfuric acid)
  • HClO₃ (Chloric acid)
  • HClO₄ (Perchloric acid)

Strong and Weak Bases

  • Strong Base: A base that is 100% ionized in solution.
  • Weak Base: A base that is less than 100% ionized in solution. Bases that do not contain hydroxide ions in their formula, such as NH₃, are typically weak bases.

Examples of Strong Bases

  • LiOH (Lithium hydroxide)
  • NaOH (Sodium hydroxide)
  • KOH (Potassium hydroxide)
  • RbOH (Rubidium hydroxide)
  • CsOH (Cesium hydroxide)
  • Mg(OH)₂ (Magnesium hydroxide)
  • Ca(OH)₂ (Calcium hydroxide)
  • Sr(OH)₂ (Strontium hydroxide)
  • Ba(OH)₂ (Barium hydroxide)

Identifying Strong and Weak Acids/Bases

  • A chemical listed in the table of strong acids and bases is strong.
  • If not listed, it is considered weak.

Example 14.7.1: Identifying Strong and Weak Acids and Bases

  • HCl: Strong acid
  • Mg(OH)₂: Strong base
  • C₅H₅N (Pyridine): Weak base (because it does not contain OH ions)

Exercise Example

  • RbOH: Strong base
  • HNO₂: Weak acid

Base Ionization Example

  • Ca(OH)₂ dissociates as follows:
    • Ca(OH)₂ → Ca²⁺ + 2OH⁻
    • As it is a strong base, it dissociates 100%.

Exercise Example

  • HN₃ dissociates as follows:
    • HN₃ ⇌ H⁺ + N₃⁻
    • Does not dissociate 100% because it is a weak acid.

Key Takeaways

  • Strong acids and bases are 100% ionized in aqueous solution.
  • Weak acids and bases are less than 100% ionized.
  • Salts of weak acids or bases can influence the acidity or basicity of their solutions.

Contributions & Attributions

  • Content shared under CK-12 license by Marisa Alviar-Agnew & Henry Agnew.