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Intramolecular vs Intermolecular Forces

Sep 2, 2025

Overview

This lecture explains the difference between intramolecular and intermolecular forces, emphasizing definitions, locations, and key distinctions pertinent to chemistry.

Intramolecular Forces

  • Intramolecular forces exist within a single molecule.
  • These forces hold atoms together inside a molecule.
  • Intramolecular forces are also known as chemical bonds (ionic, covalent, or metallic bonds).
  • Example: The bond between hydrogen and oxygen atoms in a water molecule is an intramolecular force.

Intermolecular Forces

  • Intermolecular forces exist between two or more different molecules.
  • These forces attract separate molecules to each other but do not involve electron sharing or transfer.
  • Intermolecular forces are not chemical bonds; they are attractions resulting from regions of opposite charge.
  • Example: The attraction between two water molecules is due to intermolecular forces.

Key Differences

  • Intramolecular forces occur within molecules; intermolecular forces occur between molecules.
  • Intramolecular forces involve actual chemical bonds; intermolecular forces are weaker attractions.

Key Terms & Definitions

  • Intramolecular Force — A force (bond) holding atoms together within a molecule (e.g., covalent bond).
  • Intermolecular Force — A force attracting separate molecules toward each other, not involving bonds.
  • Bond — A connection between atoms that involves sharing or transfer of electrons (ionic, covalent, metallic).

Action Items / Next Steps

  • Write down definitions and key differences for use in future assignments or exams.