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Understanding Electron Configuration in Chemistry

Jun 3, 2025

BTEC Applied Science Unit One: Chemistry Electron Configuration

Overview

  • Electrons in Atoms: Electrons revolve around an atom in energy levels called shells.
  • Shells: Labeled as n = 1, 2, 3, etc.
  • Subshells: Within shells, called s, p, d, f (focus on s, p, d).
  • Orbitals: Each subshell contains orbitals. Each orbital can hold a maximum of two electrons.

Shells and Subshells

  • N=1 Shell: Contains only an s subshell.
  • N=2 Shell: Contains s and p subshells.
  • N=3 Shell: Contains s, p, and d subshells.

Orbitals

  • S Subshell: 1 orbital
  • P Subshell: 3 orbitals
  • D Subshell: 5 orbitals
  • F Subshell: Implied to have more orbitals, beyond basic course requirements.

Electron Capacity

  • First Shell: Holds 2 electrons (s orbital only).
  • Second Shell: Holds 8 electrons (s and p orbitals: 2 + 6).
  • Third Shell: Holds 18 electrons (s, p, and d orbitals: 2 + 6 + 10).

Example Configurations

Fluorine

  • Electrons: 9
  • Configuration: 1s² 2s² 2p⁵
  • Filling Order: Fill lower energy levels first, with electrons spinning oppositely (up and down arrows).

Calcium

  • Electrons: 20
  • Configuration: 1s² 2s² 2p⁶ 3s² 3p⁶ 4s²
  • Filling Order: 4s subshell fills before 3d.

Magnesium Ion (Mg²⁺)

  • Electrons: 10
  • Configuration: 1s² 2s² 2p⁶
  • Similar to: Neon

Practice

  • Drawing Electron Configurations: Practice drawing electron configurations for the first 20 elements.
  • Ions: Consider group numbers for ion charges (Group 1: +1, Group 2: +2, Group 7: -2, Group 0: Noble gases, typically do not form ions).

Tips

  • Visualization: Electron configuration is akin to people choosing empty seats on a bus (fill up seats that are free).
  • Practice Makes Perfect: Repeated practice will solidify understanding, especially useful for exams.

Reminder

  • Group Terminology: Group 0 refers to inert gases; avoid confusion with "Group 8".