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Atomic Structure and Notation

Sep 12, 2025

Overview

This lecture explains the structure of the atom, the identity and notation of elements, and how to determine the numbers of subatomic particles.

Atomic Structure

  • The nucleus, located at the atom's center, contains protons (positive charge) and neutrons (no charge).
  • The nucleus is dense due to the mass of protons and neutrons.
  • Electrons (negative charge) orbit the nucleus and are in constant motion.

Subatomic Particles and Element Identity

  • Elements are defined by their number of protons.
  • The number of protons is called the atomic number, abbreviated as Z.
  • Changing the number of protons changes the element to a different one.

Elemental Symbol Notation

  • Element symbols are written as:
    [ ^A_Z X ]
    where X = element symbol, A = atomic mass number, Z = atomic number.
  • Mass number (A) = protons + neutrons.
  • Atomic number (Z) = number of protons.
  • The number of neutrons = mass number (A) minus atomic number (Z).

Examples

  • Oxygen (O): Atomic number Z = 8;
    if mass number A = 17, neutrons = 17 - 8 = 9.
  • For a neutral oxygen atom, electrons = protons = 8.
  • Californium (Cf): Z = 98, A = 251;
    neutrons = 251 - 98 = 153;
    neutral atom electrons = 98.

Charge and Electrons

  • The charge is shown in the notation as a superscript; if blank, the atom is neutral.
  • Neutral atoms have equal numbers of protons and electrons.

Key Terms & Definitions

  • Proton — positively charged subatomic particle found in the nucleus.
  • Neutron — neutral subatomic particle found in the nucleus.
  • Electron — negatively charged subatomic particle orbiting the nucleus.
  • Atomic number (Z) — number of protons in an atom, defines the element.
  • Mass number (A) — total number of protons and neutrons in the nucleus.

Action Items / Next Steps

  • Prepare for a discussion on atoms with unequal protons and electrons (ions) in the next class.